2-Dodecene, (Z)-
- Formula: C12H24
- Molecular weight: 168.3190
- IUPAC Standard InChIKey: ADOQBZAVKYCFOI-HYXAFXHYSA-N
- CAS Registry Number: 7206-26-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (2Z)-2-Dodecene; cis-2-Dodecene; (Z)-2-Dodecene
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Squalane | 100. | 1202. | Heinzen, Soares, et al., 1999 | |
Capillary | SE-30 | 120. | 1211. | Gusev, Sokolov, et al., 1989 | H2; Column length: 40. m; Column diameter: 0.30 mm |
Capillary | OV-101 | 110. | 1211. | Rang, Kuningas, et al., 1987 | He; Column length: 50. m; Column diameter: 0.25 mm |
Capillary | OV-1 | 60. | 1222. | Nijs and Jacobs, 1981 | He; Column length: 150. m; Column diameter: 0.50 mm |
Capillary | Squalane | 100. | 1202. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 115. | 1202. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 130. | 1203. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 86. | 1202. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Apiezon L | 120. | 1210.5 | Eisen, Orav, et al., 1972 | Column length: 45. m; Column diameter: 0.25 mm |
Capillary | Squalane | 100. | 1201.7 | Soják and Hrivnák, 1972 | H2; Column length: 200. m; Column diameter: 0.2 mm |
Capillary | Squalane | 115. | 1202.3 | Soják and Hrivnák, 1972 | H2; Column length: 200. m; Column diameter: 0.2 mm |
Capillary | Squalane | 130. | 1202.8 | Soják and Hrivnák, 1972 | H2; Column length: 200. m; Column diameter: 0.2 mm |
Capillary | Squalane | 86. | 1201.1 | Soják and Hrivnák, 1972 | H2; Column length: 200. m; Column diameter: 0.2 mm |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | PEG-20M | 80. | 1262.3 | Orav, Kuningas, et al., 1994 | 50. m/0.2 mm/0.13 μm, He |
Capillary | PEG-20M | 80. | 1265.7 | Orav, Kuningas, et al., 1994 | 50. m/0.2 mm/0.19 μm, He |
Capillary | PEG-20M | 80. | 1267.2 | Orav, Kuningas, et al., 1994 | 50. m/0.2 mm/0.22 μm, He |
Capillary | PEG 4000 | 100. | 1279. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 110. | 1280. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 120. | 1281. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 140. | 1283. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 160. | 1285. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 100. | 1274. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 110. | 1275. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 120. | 1275. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 130. | 1276. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 140. | 1278. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 90. | 1272. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 100. | 1279. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | PEG 4000 | 120. | 1281. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | PEG 4000 | 140. | 1283. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | PEG 4000 | 160. | 1285. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | Polyethylene Glycol 4000 | 100. | 1281.5 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | Polyethylene Glycol 4000 | 120. | 1283.3 | Eisen, Orav, et al., 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 100. | 1281.5 | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 120. | 1283.3 | Orav and Eisen, 1972 | Column length: 80. m; Column diameter: 0.25 mm |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 1213. | Zaikin and Borisov, 2002 | He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Petrocol DH | 1212. | Sojak, Kubinec, et al., 2006 | 150. m/0.25 mm/1.0 μm, 1. K/min; Tstart: 40. C; Tend: 300. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane | 1202. | Junkes, Castanho, et al., 2003 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A.,
Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes,
J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0
. [all data]
Gusev, Sokolov, et al., 1989
Gusev, G.M.; Sokolov, V.P.; Yurov, V.V.; Kuznetsov, A.V.; Potatuev, A.A.,
Identification of olefins during hydrocarboxylation,
Zh. Anal. Khim., 1989, 44, 551-555. [all data]
Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O.,
Retention and Thermodynamics of Solution of n-Alkenes in OV-101,
J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4
. [all data]
Nijs and Jacobs, 1981
Nijs, H.H.; Jacobs, P.A.,
On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor,
J. Chromatogr. Sci., 1981, 19, 1, 40-45, https://doi.org/10.1093/chromsci/19.1.40
. [all data]
Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J.,
Capillary Gas Chromatography of Linear Alkenes on Squalane,
Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039
. [all data]
Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S.,
Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire,
Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600
. [all data]
Soják and Hrivnák, 1972
Soják, L.; Hrivnák, J.,
Open tubular column gas chromatography of the catalytic dehydrogenation products of n-dodecane,
J. Chromatogr. Sci., 1972, 10, 11, 701-704, https://doi.org/10.1093/chromsci/10.11.701
. [all data]
Orav, Kuningas, et al., 1994
Orav, A.; Kuningas, K.; Kailas, T.; Koplimets, E.; Rang, S.,
Effect of adsorption on the retention values in capillary columns coated with OV-225 and PEG 20M,
J. Chromatogr. A, 1994, 659, 1, 143-150, https://doi.org/10.1016/0021-9673(94)85016-X
. [all data]
Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G.,
Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]
Rang, Kuningas, et al., 1977
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O.,
Capillary Gas Chromatography of C6-C14 n-Alkenes on Polyphenyl Ether and Polyethylene Glycol 4000,
Chromatographia, 1977, 10, 2, 55-64, https://doi.org/10.1007/BF02274460
. [all data]
Orav and Eisen, 1972
Orav, A.; Eisen, O.,
The retention indexes for alkenes, alkynes and cyclenes on capillary columns,
Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]
Zaikin and Borisov, 2002
Zaikin, V.G.; Borisov, R.S.,
Chromatographic-mass spectrometric analysis of Fishcer-Tropsch synthesis products,
J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 6, 544-551. [all data]
Sojak, Kubinec, et al., 2006
Sojak, L.; Kubinec, R.; Jurdakova, H.; Hajekova, E.; Bajus, M.,
GC-MS of polyethylene and polypropylene thermal cracking produxts,
Petroleum Coal, 2006, 48, 1, 1-14. [all data]
Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F.,
Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies,
Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]
Notes
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