Fe(CO) anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas34.8 ± 3.5kcal/molR-EAVillalta and Leopold, 1993 
Δfgas16.2 ± 6.0kcal/molEIAECompton and Stockdale, 1976From Fe(CO)5

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CFeO- • 4294967295Carbon monoxide) + Carbon monoxide = CFeO-

By formula: (CFeO- • 4294967295CO) + CO = CFeO-

Quantity Value Units Method Reference Comment
Δr34.8 ± 3.5kcal/molN/AVillalta and Leopold, 1993gas phase
Δr33.7 ± 3.5kcal/molCIDTSunderlin, Wang, et al., 1992gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(CFeO- • 4294967295Carbon monoxide) + Carbon monoxide = CFeO-

By formula: (CFeO- • 4294967295CO) + CO = CFeO-

Quantity Value Units Method Reference Comment
Δr34.8 ± 3.5kcal/molN/AVillalta and Leopold, 1993gas phase
Δr33.7 ± 3.5kcal/molCIDTSunderlin, Wang, et al., 1992gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Villalta and Leopold, 1993
Villalta, P.W.; Leopold, D.G., A Study of FeCO- and the 3-Sigma(-) and 5-Sigma(-) States of FeCO by Negative Ion Photoelectron Spectroscopy, J. Chem. Phys., 1993, 98, 10, 7730, https://doi.org/10.1063/1.464580 . [all data]

Compton and Stockdale, 1976
Compton, R.N.; Stockdale, J.A.D., Formation of gas phase negative ions in Fe(CO)5 and Ni(CO)4, Int. J. Mass Spectrom. Ion Phys., 1976, 22, 47. [all data]

Sunderlin, Wang, et al., 1992
Sunderlin, L.S.; Wang, D.; Squires, R.R., Metal Carbonyl Bond Strengths in Fe(CO)n- and Ni(CO)n-, J. Am. Chem. Soc., 1992, 114, 8, 2788, https://doi.org/10.1021/ja00034a004 . [all data]


Notes

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