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1-Butanol

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Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Deltafgas (kJ/mol) Method Reference Comment
-275.6N/AMosselman and Dekker, 1975Value computed using «DELTA»fHliquid° value of -327.0±0.2 kj/mol from Mosselman and Dekker, 1975 and «DELTA»vapH° value of 51.4 kj/mol from Skinner and Snelson, 1960.; DRB
-274.7 ± 0.3CcbMosselman and Dekker, 1975Value computed using «DELTA»fHliquid° from Mosselman and Dekker, 1975 and «DELTA»vapH° value of 52.3 kJ/mol from Wadso, 1966.; DRB
-275.28 ± 0.53CcbGundry, Harrop, et al., 1969ALS
-275.8N/AMosselman and Dekker, 1969Value computed using «DELTA»fHliquid° value of -327.2±0.2 kj/mol from Mosselman and Dekker, 1969 and «DELTA»vapH° value of 51.4 kj/mol from Skinner and Snelson, 1960.; DRB
-274.9 ± 0.3CcbMosselman and Dekker, 1969Value computed using «DELTA»fHliquid° from Mosselman and Dekker, 1969 and «DELTA»vapH° value of 52.3 kJ/mol from Wadso, 1966.; DRB
-274.4N/AChao and Rossini, 1965Value computed using «DELTA»fHliquid° value of -325.8±0.7 kj/mol from Chao and Rossini, 1965 and «DELTA»vapH° value of 51.4 kj/mol from Skinner and Snelson, 1960.; DRB
-273.5 ± 0.7CcbChao and Rossini, 1965Value computed using «DELTA»fHliquid° from Chao and Rossini, 1965 and «DELTA»vapH° value of 52.3 kJ/mol from Wadso, 1966.; DRB
-280.0 ± 0.92CcbGreen, 1960ALS
-277. ± 1.5CcbSkinner and Snelson, 1960ALS
-281.4N/ATjebbes, 1960Value computed using «DELTA»fHliquid° value of -332.8±0.4 kj/mol from Tjebbes, 1960 and «DELTA»vapH° value of 51.4 kj/mol from Skinner and Snelson, 1960.; DRB
-280.5 ± 0.4CcbTjebbes, 1960Value computed using «DELTA»fHliquid° from Tjebbes, 1960 and «DELTA»vapH° value of 52.3 kJ/mol from Wadso, 1966.; DRB
-278.2N/AParks, 1925Value computed using «DELTA»fHliquid° value of -329.6 kj/mol from Parks, 1925 and «DELTA»vapH° value of 51.4 kj/mol from Skinner and Snelson, 1960.; DRB
-277.3 ± 3.0CcbParks, 1925Value computed using «DELTA»fHliquid° from Parks, 1925 and «DELTA»vapH° value of 52.3 kJ/mol from Wadso, 1966. estimated uncertainty; DRB

References

Go To: Top, Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Skinner and Snelson, 1960
Skinner, H.A.; Snelson, A., The heats of combustion of the four isomeric butyl alcohols, Trans. Faraday Soc., 1960, 56, 1776-1783. [all data]

Wadso, 1966
Wadso, I., Acta Chem. Scand., 1966, 20, 544. [all data]

Gundry, Harrop, et al., 1969
Gundry, H.A.; Harrop, D.; Head, A.J.; Lewis, G.B., Thermodynamic properties of organic oxygen compounds. 21. Enthalpies of combustion of benzoic acid, pentan-1-ol, octan-1-ol, and hexadecan-1-ol, J. Chem. Thermodyn., 1969, 1, 321-332. [all data]

Mosselman and Dekker, 1969
Mosselman, C.; Dekker, H., A new method for handling volatile and hygroscopic substances in bomb calorimetry enthalpy of formation of liquid butanol, Recl. Trav. Chim. Pays-Bas, 1969, 257-261. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Tjebbes, 1960
Tjebbes, J., Heats of combustion of butannal and some related compounds, Acta Chem. Scand., 1960, 14, 180-188. [all data]

Parks, 1925
Parks, G.S., Thermal data on organic compounds I. The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols, J. Am. Chem. Soc., 1925, 47, 338-345. [all data]


Notes

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