1-Butanol

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Normal alkane RI, polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxDB-WaxHP-Innowax
Column length (m) 60.30.30.30.60.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.200.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program 40 0C (3 min) 2 0C/min -> 150 0C 4 0C/min -> 220 0C (20 min) 5 0C/min -> 230 0Cnot specifiednot specifiednot specifiednot specified
I 1145.1148.1149.1159.1158.
ReferenceGyawali and Kim, 2012Welke, Manfroi, et al., 2012Welke, Manfroi, et al., 2012Welke, Manfroi, et al., 2012Feng, Zhuang, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SOLGel-WaxSOLGel-WaxSOLGel-WaxCP-Wax 52 CBDB-Wax
Column length (m) 30.30.30. 30.
Carrier gas HeliumHeliumHelium Hydrogen
Substrate      
Column diameter (mm) 0.250.250.25 0.25
Phase thickness (μm) 0.250.250.25 0.25
Program 40 0C (2 min) 5 0C/min -> 140 0C 10 0C/min -> 250 0C (3 min)40 0C (2 min) 5 0C/min -> 140 0C 10 0C/min -> 250 0C (3 min)not specifiednot specified35 0C (9 min) 5 0C/min -> 80 0C 1 0C/min -> 100 0C 16 0C/min -> 210 0C (20 min)
I 1153.1153.1152.1163.1159.
ReferenceJohanningsmeier and McFeeters, 2011Johanningsmeier and McFeeters, 2011Johanningsmeier and McFeeters, 2011Povolo, Cabassi, et al., 2011Sampaio, Garruti, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase StabilwaxFFAPDB-WaxDB-WaxSupelcowax-10
Column length (m) 30.50.20.20.50.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.200.180.180.25
Phase thickness (μm) 0.250.330.180.180.25
Program 35 0C 3 0C/min -> 100 0C 5 0C/min -> 240 0C (10 min)70 0C (1 min) 3 0C/min -> 142 0C 5 0C/min -> 225 0C (10 min)35 0C (1 min) 2.9 0C/min -> 100 0C 8 0C/min -> 200 0C (5 min)35 0C (1 min) 2/9 0C/min -> 100 0C 8 0C/min -> 200 0C (5 min)45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)
I 1142.1119.1135.1135.1166.
ReferenceChinnici, Guerrero, et al., 2009Ortiz, Echeverra, et al., 2009Rowan, Hunt, et al., 2009Rowan, Hunt, et al., 2009, 2Soria, Martinez-Castro, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxCP-Wax 52 CBDB-WaxSupelcowax 10
Column length (m) 30.30.50.30.50.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.320.250.250.320.25
Phase thickness (μm) 0.500.250.290.250.25
Program 40 0C 7 0C/min -> 110 0C 15 0C/min -> 250 0C (3 min)not specified33 0C (1 min) 2 0C/min -> 130 0C 10 0C/min -> 220 0C40 0C (3 min) 4 0C/min -> 160 0C 7 0C/min -> 220 0C (8 min)45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)
I 1158.1147.1124.1165.1166.
ReferenceValappil, Fan, et al., 2009Zhao, Xu, et al., 2009Kaack and Christensen, 2008Li, Tao, et al., 2008Soria, Martinez-Castro, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax 10DB-WaxDB-WaxSupelcowax-10Supelcowax-10
Column length (m) 50.30.30.30.30.
Carrier gas HeliumHeliumHeliumHeHe
Substrate      
Column diameter (mm) 0.250.320.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program 45 0C (15 min) 3 0C/min -> 75 0C 5 0C/min -> 180 0C (10 min)50 0C 20 0C/min -> 80 0C 3 0C/min -> 230 0C40 0C (4 min) 3 0C/min -> 50 0C 5 0C/min -> 120 0C 7 0C/min -> 175 0C 10 0C/min -> 230 0C (8 min)35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)
I 1166.1152.1165.1152.1153.
ReferenceSoria, Martinez-Castro, et al., 2008Tao, Wenlai, et al., 2008Yongsheng, Hua, et al., 2008Berard, Bianchi, et al., 2007Berard, Bianchi, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10FFAPDB-WaxFFAPDB-Wax Etr
Column length (m) 30.50.30.50.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.20.320.20.25
Phase thickness (μm) 0.250.330.250.330.5
Program 40C(10min) => 2C/min => 200C(1min) => 2C/min => 250C (10min)70C(1min) => 3C/min => 142C => 5C/min => 225C (10min)40C(3min) => 4C/min => 160C => 7C/min => 230C (8min)70C(1min) => 3C/min => 142C => 5C/min => 225C(10min)40C(3min) => 10C/min => 90C => 2C/min => 230C (37min)
I 1159.1144.1165.1144.1116.
ReferenceBosch-Fuste, Riu-Aumatell, et al., 2007Lara, Echeverría, et al., 2007Li, Tao, et al., 2007Lopez, Villatoro, et al., 2007Loskos, Hernandez-Orte, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-InnowaxDB-WaxFFAPHP-Innowax
Column length (m) 30.30.30.50.60.
Carrier gas HeHeHeHeNitrogen
Substrate      
Column diameter (mm) 0.250.250.320.20.25
Phase thickness (μm) 0.250.50.250.330.25
Program 50 0C (2 min) 6 0C/min -> 150 0C 8 0C/min -> 230 0C (15 min)30C(2min) => 4C/min => 130C => 8C/min => 250C(5min)45C(5min) => 5C/min => 150C => 10C/min => 240C (10min)70C(1min) => 3C/min => 142C => 5C/min => 225C(10min)50 0C (4 min) -> 40 0C 4 0C/min -> 220 0C
I 1143.1145.1134.1144.1135.
ReferenceTian, Zhang, et al., 2007Weldegergis B.T., Tredoux A.G.J., et al., 2007Krings, Zelena, et al., 2006Lara, Graell, et al., 2006Quijano and Pino, 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBDB-WaxFFAPDB-WaxDB-Wax
Column length (m)  60.50.60.30.
Carrier gas HydrogenHeHeHeliumHe
Substrate      
Column diameter (mm)  0.250.20.250.32
Phase thickness (μm)  0.250.330.250.5
Program not specified35C(5min) => 2C/min => 50C => 5C/min => 200C (5min)70C(1min) => 3C/min => 142C => 5C/min => 225C(10min)60 0C (3 min) 2 0C/min -> 150 0C 4 0C/min -> 200 0C40C => 1C/min => 57C => 15C/min => 230C (5min)
I 1110.1149.1144.1144.1181.
ReferenceJales, Maia, et al., 2005Mattheis, Fan, et al., 2005Echeverría, Correa, et al., 2004Kim. J.H., Ahn, et al., 2004le Pape, Grua-Priol, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MHP-FFAPPEG-20MDB-WaxHP Innowax FSP
Column length (m)  50.30.30.60.
Carrier gas  He HeHe
Substrate      
Column diameter (mm)  0.20.250.320.25
Phase thickness (μm)  0.330.250.50.25
Program not specified70C(1min) => 3C/min => 142C => 5C/min => 225C (10min)50C(8min) => 4C/min => 110C => 16C/min => 200C60C(2min) => 2C/min => 220C => 3C/min => 245C(20min)60C(10min) => 4C/min => 220C (10min) => 1C/min => 240C
I 1141.1144.1157.1136.1155.
ReferenceVinogradov, 2004Echeverria, Fuentes, et al., 2003Garruti, Franco, et al., 2003Selli, Cabaroglu, et al., 2003Tasdemir, Demirci, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP Innowax FSPDB-WaxDB-WaxDB-WaxFFAP
Column length (m) 60.30.30.30.50.
Carrier gas He  HeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.33
Program 60C(10min) => 4C/min => 220C (10min) => 1C/min => 240C50C(4min) => 4C/min => 130C => 1C/min => 190C => 4C/min => 220C(20min)50C(4min) => 4C/min => 130C => 1C/min => 190C => 4C/min => 220C(20min)25 0C (0.5 min) 50 K/min -> 50 0C 3.5 K/min -> 150 0C 7.5 K/min -> 240 0C70C(1min) => 3C/min => 142C(2min) => 25C/min => 230C(5min)
I 1155.1139.1148.1113.1148.
ReferenceTasdemir, Demirci, et al., 2003Mayorga, Knapp, et al., 2001Mayorga, Knapp, et al., 2001Miranda, Nogueira, et al., 2001Lopez, Lavilla, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Cross-linked FFAPFFAPPEGPEGDB-Wax
Column length (m) 50.50.40.40.60.
Carrier gas N2N2HydrogenHydrogenHe
Substrate      
Column diameter (mm) 0.20.20.1820.1820.25
Phase thickness (μm) 0.330.330.300.30 
Program 70C(1min) => 3C/min => 142C (2min) => 25C/min => 230C(5min)70C (1min) => 3C/min => 142C (2min) => 25C/min => 230C (5min)35 0C (5 min) 5 0C/min -> 100 0C 3 0C/min -> 200 0C (1 min) 20 0C/min -> 240 0C (2 min)35 0C (5 min) 5 0C/min -> 100 0C 3 0C/min -> 200 0C (1 min) 20 0C/min -> 240 0C (2 min)45C(4min) => 30C/min => 60C (5min) => 3C/min => 220C(40min)
I 1148.1148.1163.1163.1151.
ReferenceLavilla, Puy, et al., 1999López, Lavilla, et al., 1998Vas, Gal, et al., 1998Vas, Gal, et al., 1998Ziegleder, 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10Polyethylene GlycolCP-Wax 52CBDB-WaxDB-Wax
Column length (m) 30. 50.60.60.
Carrier gas He  HeHe
Substrate      
Column diameter (mm) 0.32 0.320.250.25
Phase thickness (μm) 0.25 1.50.250.25
Program 50C(2min) => 7C/min => 140C => 17.5C/min => 230Cnot specified40C => 2C/min => 150C => 10C/min => 250C35C (5min) => 2C/min => 50C => 5C/min => 200C(5min)35C (5min) => 2C/min => 50C => 5C/min => 200C(5min)
I 1113.1141.1125.1148.1148.
ReferenceChang, Seitz, et al., 1995Zenkevich, Korolenko, et al., 1995Luning, de Rijk, et al., 1994Mattheis, Buchanan, et al., 1992Mattheis, Buchanan, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxCarbowax 20MCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.
Column length (m)   60. 50.
Carrier gas     Hydrogen
Substrate      
Column diameter (mm)   0.32 0.32
Phase thickness (μm)      
Program not specifiednot specifiednot specifiednot specifiednot specified
I 1135.1141.1139.1113.1178.
ReferencePeng, Yang, et al., 1991Peng, Yang, et al., 1991Binder, Flath, et al., 1989Shibamoto, 1987Waggott and Davies, 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase Carbowax 20M
Column length (m)  
Carrier gas  
Substrate  
Column diameter (mm)  
Phase thickness (μm)  
Program not specified
I 1128.
ReferenceRamsey and Flanagan, 1982
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gyawali and Kim, 2012
Gyawali, R.; Kim, K.-S., Bioactive volatile compounds of three medicinal plants from Nepal, Kathmandu Univ. J. Sci., Engineering and Technol., 2012, 8, 1, 51-62. [all data]

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Kaack and Christensen, 2008
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Li, Tao, et al., 2008
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Lara, Graell, et al., 2006
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Jales, Maia, et al., 2005
Jales, K.A.; Maia, G.A.; Garruti, D.S.; Neto, M.A.S.; Janzantti, N.S.; Franco, M.R.B., Evaluation de los compuestos odoriferos del jugo de maracuya amarillo por GC-MS y GC-O (OSME), Alimentis y bebidas, 2005, 3, 12-14. [all data]

Mattheis, Fan, et al., 2005
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Echeverría, Correa, et al., 2004
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Kim. J.H., Ahn, et al., 2004
Kim. J.H.; Ahn, H.J.; Yook, H.S.; Kim, K.S.; Rhee, M.S.; Ryu, G.H.; Byun, M.W., Color, flavor, and sensory characteristics of gamma-irradiated salted and fermented anchovy sauce, Radiation Phys. Chem., 2004, 69, 2, 179-187, https://doi.org/10.1016/S0969-806X(03)00400-6 . [all data]

le Pape, Grua-Priol, et al., 2004
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Notes

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