n-Octatetracontane
- Formula: C48H98
- Molecular weight: 675.2917
- IUPAC Standard InChIKey: CFBPOLLJQOANPF-UHFFFAOYSA-N
- CAS Registry Number: 7098-26-2
- Chemical structure:
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
1595. | 353. | Atkinson, Larkin, et al., 1969 | T = 353 to 453 K. Equation only. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 361.4 | K | N/A | Lukes and Dolezal, 1957 | Uncertainty assigned by TRC = 3. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 243.0 ± 0.2 | kJ/mol | CGC | Chickos, Wang, et al., 2008 | Based on data from 323. to 523. K.; AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
145.9 | 610. | A,E | Stephenson and Malanowski, 1987 | Based on data from 595. to 843. K. See also Kudchadker and Zwolinski, 1966.; AC |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Atkinson, Larkin, et al., 1969
Atkinson, C.M.L.; Larkin, J.A.; Richardson, M.J.,
Enthalpy changes in molten n-alkanes and polyethylene,
J. Chem. Thermodynam., 1969, 1, 435-445. [all data]
Lukes and Dolezal, 1957
Lukes, R.; Dolezal, S.,
The Action of Grignard Reagents on the Amide Group XXI. Synthesis of Some Higher Monocarboxylic Acids,
Chem. Listy, 1957, 51, 2065. [all data]
Chickos, Wang, et al., 2008
Chickos, James; Wang, Tracy; Sharma, Esseim,
Hypothetical Thermodynamic Properties: Vapor Pressures and Vaporization Enthalpies of the Even n -Alkanes from C 40 to C 76 at T = 298.15 K by Correlation-Gas Chromatography. Are the Vaporization Enthalpies a Linear Function of Carbon Number?,
J. Chem. Eng. Data, 2008, 53, 2, 481-491, https://doi.org/10.1021/je7005852
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kudchadker and Zwolinski, 1966
Kudchadker, A.P.; Zwolinski, B.J.,
Vapor Pressure and Boiling Points of Normal Alkanes, C 21 to C 100 .,
J. Chem. Eng. Data, 1966, 11, 2, 253-255, https://doi.org/10.1021/je60029a039
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Tfus Fusion (melting) point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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