diethyl sulphoxide
- Formula: C4H10OS
- Molecular weight: 106.187
- IUPAC Standard InChIKey: CCAFPWNGIUBUSD-UHFFFAOYSA-N
- CAS Registry Number: 70-29-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Diethyl sulfoxide
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 484. | K | N/A | Mackle and O'Hare, 1961 | Uncertainty assigned by TRC = 1. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 14.9 ± 0.3 | kcal/mol | V | Mackle and O'Hare, 1961, 2 | ALS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
14.0 ± 0.79 | 308. | Markarian, Zatikyan, et al., 2005 | Based on data from 298. to 318. K.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G.,
Studies in the thermochemistry of sulphoxides. Part 1.- The gas-phase heats of formation of diethyl, di-n-propyl, t-butyl ethyl, allyl ethyl and diphenyl sulphoxides,
Trans. Faraday Soc., 1961, 57, 2119. [all data]
Mackle and O'Hare, 1961, 2
Mackle, H.; O'Hare, P.A.G.,
Studies in the thermochemistry of sulphoxides. Part 1 - The gas-phase heats of formation of diethyl, di-n-propyl, t-butyl ethyl, allyl ethyl and diphenyl sulphoxides,
Trans. Faraday Soc., 1961, 57, 2219-2224. [all data]
Markarian, Zatikyan, et al., 2005
Markarian, Shiraz A.; Zatikyan, Ashkhen L.; Grigoryan, Vazganush V.; Grigoryan, Gevorg S.,
Vapor Pressures of Pure Diethyl Sulfoxide from (298.15 to 318.15) K and Vapor-Liquid Equilibria of Binary Mixtures of Diethyl Sulfoxide with Water,
J. Chem. Eng. Data, 2005, 50, 1, 23-25, https://doi.org/10.1021/je034278t
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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