diethyl sulphoxide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-205. ± 2.kJ/molCcrMackle and O'Hare, 1961 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-267.6 ± 0.8kJ/molCcrMackle and O'Hare, 1961 
Quantity Value Units Method Reference Comment
Δcliquid-3337.5 ± 0.4kJ/molCcrMackle and O'Hare, 1961 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil484.KN/AMackle and O'Hare, 1961, 2Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δvap62. ± 1.kJ/molVMackle and O'Hare, 1961ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
58.7 ± 3.3308.Markarian, Zatikyan, et al., 2005Based on data from 298. to 318. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphoxides. Part 1 - The gas-phase heats of formation of diethyl, di-n-propyl, t-butyl ethyl, allyl ethyl and diphenyl sulphoxides, Trans. Faraday Soc., 1961, 57, 2219-2224. [all data]

Mackle and O'Hare, 1961, 2
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphoxides. Part 1.- The gas-phase heats of formation of diethyl, di-n-propyl, t-butyl ethyl, allyl ethyl and diphenyl sulphoxides, Trans. Faraday Soc., 1961, 57, 2119. [all data]

Markarian, Zatikyan, et al., 2005
Markarian, Shiraz A.; Zatikyan, Ashkhen L.; Grigoryan, Vazganush V.; Grigoryan, Gevorg S., Vapor Pressures of Pure Diethyl Sulfoxide from (298.15 to 318.15) K and Vapor-Liquid Equilibria of Binary Mixtures of Diethyl Sulfoxide with Water, J. Chem. Eng. Data, 2005, 50, 1, 23-25, https://doi.org/10.1021/je034278t . [all data]


Notes

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