D-Mannitol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-319.67kcal/molCcbMcClaine, 1947ALS
Δfsolid-319.61 ± 0.19kcal/molCcbParks, West, et al., 1946ALS
Quantity Value Units Method Reference Comment
Δcsolid-729.6kcal/molCcbBaer and Flehmig, 1969Corresponding Δfsolid = -312.9 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-727.95kcal/molCmParks and Manchester, 1952From heat of solution; Corresponding Δfsolid = -314.56 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-722.9 ± 0.4kcal/molCcbMcClaine, 1947Corresponding Δfsolid = -319.6 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-722.93 ± 0.43kcal/molCcbParks, West, et al., 1946Corresponding Δfsolid = -319.58 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar57.00cal/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 64.02 J/mol*K. Revision of previous data.; DH
solid,1 bar60.49cal/mol*KN/AParks and Anderson, 1926Extrapolation below 90 K, 78.66 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
57.122298.15Lian, Chen, et al., 1982DH
58.51303.Spaght, Thomas, et al., 1932T = 30 to 200°C.; DH
56.41294.1Parks and Anderson, 1926T = 88 to 294 K. Value is unsmoothed experimental datum.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus439.1KN/ABarone, DellaGatta, et al., 1990Uncertainty assigned by TRC = 0.1 K; TRC
Tfus439.KN/ASchwarz, Grundstein, et al., 1972Uncertainty assigned by TRC = 1. K; TRC
Tfus439.2KN/ASpaght, Thomas, et al., 1932, 2Uncertainty assigned by TRC = 0.2 K; TRC
Tfus439.13KN/ABurriel, 1931Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δsub48.3kcal/molBBarone, Gatta, et al., 1990AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
568.20.005Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
32.41 ± 0.26479.TEBarone, Gatta, et al., 1990Based on data from 458. to 501. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
13.408439.1N/ABarone and Della Gatta, 1990DH
12.806433.2N/ASpaght, Thomas, et al., 1932DH
13.07437.3DSCTong, Liu, et al., 2010AC
13.4439.1DSCDomalski and Hearing, 1996See also Barone, Gatta, et al., 1990.; AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
30.54439.1Barone and Della Gatta, 1990DH
29.57433.2Spaght, Thomas, et al., 1932DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McClaine, 1947
McClaine, L.A., Thermodynamic data for some compounds containing carbon, hydrogen and oxygen, Ph.D. Thesis for Stanford University, 1947, 1-57. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Baer and Flehmig, 1969
Baer, E.; Flehmig, H.-H., Refutation of alleged differences in the energy contents of optical isomers, Can. J. Biochem., 1969, 47, 79-83. [all data]

Parks and Manchester, 1952
Parks, G.S.; Manchester, K.E., The heats of solution of erythritol, mannitol and dulcitol; combustion values for liquid polyhydroxy alcohols, J. Am. Chem. Soc., 1952, 74, 3435-34. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Parks and Anderson, 1926
Parks, G.S.; Anderson, C.T., Thermal data on organic compounds. III. The heat capacities, entropies and free energies of tertiary butyl alcohol, mannitol, erythritol and normal butyric acid, J. Am. Chem. Soc., 1926, 48, 1506-1512. [all data]

Lian, Chen, et al., 1982
Lian, Y.N.; Chen, A.T.; Suurkuusk, J.; Wadsoe, I., Polyol-water interactions as reflected by aqueous heat capacity values, Acta Chem. Scand., 1982, A36(9), 735-739. [all data]

Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-888. [all data]

Barone, DellaGatta, et al., 1990
Barone, G.; DellaGatta, G.; Ferro, D.; Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86, 75. [all data]

Schwarz, Grundstein, et al., 1972
Schwarz, E.M.; Grundstein, V.V.; Ievins, A.F., Thermal investigation off polyols: 1. hexitols and pentitols., J. Therm. Anal., 1972, 4, 331-7. [all data]

Spaght, Thomas, et al., 1932, 2
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-8. [all data]

Burriel, 1931
Burriel, F., Physico-Chemical Study of Some Solid Organic Compounds at Ordinary Temperatures, and Their COrrelationo with Temperature, An. R. Soc. Esp. Fis. Quim., 1931, 29, 89. [all data]

Barone, Gatta, et al., 1990
Barone, Guido; Gatta, Giuseppe Della; Ferro, Daniela; Piacente, Vincenzo, Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, Faraday Trans., 1990, 86, 1, 75, https://doi.org/10.1039/ft9908600075 . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Barone and Della Gatta, 1990
Barone, G.; Della Gatta, G., Ferro D., and Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86(1), 75-79. [all data]

Tong, Liu, et al., 2010
Tong, Bo; Liu, Rui-Bin; Meng, Chang-Gong; Yu, Feng-Yun; Ji, Shou-Hua; Tan, Zhi-Cheng, Heat Capacities and Nonisothermal Thermal Decomposition Reaction Kinetics of, J. Chem. Eng. Data, 2010, 55, 1, 119-124, https://doi.org/10.1021/je900285w . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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