bromopentylmagnesium

Formula: C₅H₁₁BrMg
Molecular weight: 175.350
CAS Registry Number: 693-25-4
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Reaction thermochemistry data

Data compiled by: José A. Martinho Simões

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Individual Reactions

(solution) + C₅H₁₁BrMg (solution) = C₆H₅BrMgO (solution) + (solution)

By formula: C₆H₆O (solution) + C₅H₁₁BrMg (solution) = C₆H₅BrMgO (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-48.4 ± 1.0	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

(solution) + C₅H₁₁BrMg (solution) = C₂H₅BrMgO (solution) + (solution)

By formula: C₂H₆O (solution) + C₅H₁₁BrMg (solution) = C₂H₅BrMgO (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-47.7 ± 1.0	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

C₅H₁₁BrMg (solution) + (solution) = CH₄BrMgN (solution) + (solution)

By formula: C₅H₁₁BrMg (solution) + CH₅N (solution) = CH₄BrMgN (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-31.19 ± 0.60	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

C₅H₁₁BrMg (solution) + (solution) = (solution) + CH₃BrMg (solution)

By formula: C₅H₁₁BrMg (solution) + CH₄ (solution) = C₅H₁₂ (solution) + CH₃BrMg (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-3.6 ± 1.0	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

(solution) + C₅H₁₁BrMg (solution) = C₃HBrMgN₂ (solution) + (solution)

By formula: C₃H₂N₂ (solution) + C₅H₁₁BrMg (solution) = C₃HBrMgN₂ (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-48.59	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

(solution) + C₅H₁₁BrMg (solution) = C₁₂H₁₀BrMgN (solution) + (solution)

By formula: C₁₂H₁₁N (solution) + C₅H₁₁BrMg (solution) = C₁₂H₁₀BrMgN (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-28.39	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

C₅H₁₁BrMg (solution) + (solution) = C₂BrF₃MgO₂ (solution) + (solution)

By formula: C₅H₁₁BrMg (solution) + C₂HF₃O₂ (solution) = C₂BrF₃MgO₂ (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-65.39	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

C₅H₁₁BrMg (solution) + (solution) = C₆BrF₅MgO (cr) + (solution)

By formula: C₅H₁₁BrMg (solution) + C₆HF₅O (solution) = C₆BrF₅MgO (cr) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-55.90	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

C₅H₁₁BrMg (solution) + (solution) = C₂H₂BrF₃MgO (solution) + (solution)

By formula: C₅H₁₁BrMg (solution) + C₂H₃F₃O (solution) = C₂H₂BrF₃MgO (solution) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-47.71	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

(solution) + C₅H₁₁BrMg (solution) = CH₃BrMgO (cr) + (solution)

By formula: CH₄O (solution) + C₅H₁₁BrMg (solution) = CH₃BrMgO (cr) + C₅H₁₂ (solution)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	-52.51	kcal/mol	RSC	Holm, 1983	solvent: Diethyl ether

References

Go To: Top, Reaction thermochemistry data, Notes

Holm, 1983
Holm, T., Acta Chem. Scand. B, 1983, 37, 797. [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

Symbols used in this document:

Δ_rH° Enthalpy of reaction at standard conditions
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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