trans-1,2-di-tert-butylethylene
- Formula: C10H20
- Molecular weight: 140.2658
- IUPAC Standard InChI: InChI=1S/C10H20/c1-9(2,3)7-8-10(4,5)6/h7-8H,1-6H3/b8-7+
- IUPAC Standard InChIKey: UYWLQEPMPVDASH-BQYQJAHWSA-N
- CAS Registry Number: 692-48-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: 3-Hexene, 2,2,5,5-tetramethyl-, (E)-; (E)-2,2,5,5-tetramethylhex-3-ene; (E)-2,2,5,5-Tetramethyl-3-hexene
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Condensed phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔcH°liquid | -1574.06 ± 0.59 | kcal/mol | Ccb | Rockenfeller and Rossini, 1961 | Derived from the ratio of Heat of combustion; Corresponding ΔfHºliquid = -49.60 kcal/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 398.3 | K | N/A | Turner, Nettleton, et al., 1958 | Uncertainty assigned by TRC = 0.6 K; TRC |
| Tboil | 398.3 | K | N/A | Bader, Buckley, et al., 1957 | Uncertainty assigned by TRC = 0.5 K; TRC |
| Tboil | 398.3 | K | N/A | Newman, 1956 | Uncertainty assigned by TRC = 4. K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| Tfus | 268.4 | K | N/A | Turner, Nettleton, et al., 1958 | Uncertainty assigned by TRC = 0.4 K; TRC |
| Tfus | 268.4 | K | N/A | Bader, Buckley, et al., 1957 | Uncertainty assigned by TRC = 0.5 K; TRC |
| Tfus | 268. | K | N/A | Yohe, Dunbar, et al., 1956 | Uncertainty assigned by TRC = 4. K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔvapH° | 10.04 ± 0.06 | kcal/mol | C | Fuchs and Peacock, 1979 | ALS |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rockenfeller and Rossini, 1961
Rockenfeller, J.D.; Rossini, F.D.,
Heats of combustion, isomerization, and formation of selected C7, C8, and C10 monoolefin hydrocarbons,
J. Phys. Chem., 1961, 65, 267-272. [all data]
Turner, Nettleton, et al., 1958
Turner, R.B.; Nettleton, D.E.; Perelman, M.,
Heats of Hydrogenation VI. Heats of Hydr. of SOm Substituted Ethylenes,
J. Am. Chem. Soc., 1958, 80, 1430. [all data]
Bader, Buckley, et al., 1957
Bader, A.R.; Buckley, R.P.; Leavitt, F.; Szwarc, M.,
J. Am. Chem. Soc., 1957, 79, 5621. [all data]
Newman, 1956
Newman, M.,
Private Communication, Ohio State Univ., 1956. [all data]
Yohe, Dunbar, et al., 1956
Yohe, G.R.; Dunbar, J.E.; Pedrotti, R.L.; Scheidt, F.M.; Lee, F.G.H.; Smith, E.C.,
J. Org. Chem., 1956, 21, 1289. [all data]
Fuchs and Peacock, 1979
Fuchs, R.; Peacock, L.A.,
Heats of vaporization and gaseous heats of formation of some five- and six-membered ring alkenes,
Can. J. Chem., 1979, 57, 2302-2304. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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