Pyrene-pyromellitic dianhydride charge transfer complex


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar111.1cal/mol*KN/ABoerio-Goates and Westrum, 1980 
solid,1 bar111.0cal/mol*KN/ADunn, Rahman, et al., 1978 

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
106.7298.15Boerio-Goates and Westrum, 1980T = 5 to 300 K.
104.2298.15Dunn, Rahman, et al., 1978T = 5 to 300 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.05100155.crystaline, IIcrystaline, IBoerio-Goates and Westrum, 1980 

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.320155.crystaline, IIcrystaline, IBoerio-Goates and Westrum, 1980 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boerio-Goates and Westrum, 1980
Boerio-Goates, J.; Westrum, E.F., Jr., Thermodynamic studies of orientational disorder in p-molecular compounds. III. Heat capacities of naphthalene-pyromellitic dianhydride and pyrene-pyromellitic dianhydride, Mol. Cryst. Liq. Cryst., 1980, 60, 249-266. [all data]

Dunn, Rahman, et al., 1978
Dunn, A.G.; Rahman, A.; Staveley, L.A.K., The heat capacity of pyromellitic dianhydride and of its 1-1 charge-transfer complex with pyrene, J. Chem. Thermodynam., 1978, 10, 787-796. [all data]


Notes

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