Pentafluoropropionic acid, butyl ester
- Formula: C7H9F5O2
- Molecular weight: 220.1372
- IUPAC Standard InChI: InChI=1S/C7H9F5O2/c1-2-3-4-14-5(13)6(8,9)7(10,11)12/h2-4H2,1H3
- IUPAC Standard InChIKey: DUTTZBRMOIAYKM-UHFFFAOYSA-N
- CAS Registry Number: 680-28-4
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Propanoic acid, pentafluoro, butyl ester; 2,2,3,3,3-Pentafluoro-propionic acid butyl ester; Butyl pentafluoropropionate; Butyl pentafluoropropanoate
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 9.23 | 369. | A,EB | Stephenson and Malanowski, 1987 | Based on data from 354. to 389. K. See also Sheehan and Langer, 1969 and Dykyj, Svoboda, et al., 1999. |
Gas Chromatography
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-101 | 100. | 685. | Promyshlennikova, Kirichenko, et al., 1992 | |
| Capillary | OV-101 | 100. | 685.3 | Promyshlennikova, Kirichenko, et al., 1991 | He; Column length: 50. m; Column diameter: 0.25 mm |
| Packed | SE-30 | 100. | 687. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | Carbowax 20M | 100. | 760. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | 5 % Phenyl methyl siloxane | 708. | Zaikin, 2009 | 30. m/0.25 mm/0.25 μm, 15. K/min, 270. C @ 15. min; Tstart: 60. C |
References
Go To: Top, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Sheehan and Langer, 1969
Sheehan, Richard J.; Langer, Stanley H.,
Vapor pressures of fluorine- and silicon-containing derivatives of some hydroxylic compounds,
J. Chem. Eng. Data, 1969, 14, 2, 248-250, https://doi.org/10.1021/je60041a011
. [all data]
Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R.,
Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]
Promyshlennikova, Kirichenko, et al., 1992
Promyshlennikova, E.P.; Kirichenko, V.E.; Pashkevich, K.I.; Grigor'eva, D.N.; Golovnya, R.V.,
Influence of the stationary phase nature on the retention of polyfluorinated carboxylic acid esters,
Zh. Anal. Khim., 1992, 47, 1070-1075. [all data]
Promyshlennikova, Kirichenko, et al., 1991
Promyshlennikova, E.P.; Kirichenko, V.E.; Pashkevich, K.I.; Grigor'eva, D.N.; Golovnya, R.V.,
Capillary chromatography of polyfluorinated carboxylic esters,
Izv. Akad. Nauk SSSR Ser. Khim., 1991, 8, 1541-1545. [all data]
Zarazir, Chovin, et al., 1970
Zarazir, D.; Chovin, P.; Guiochon, G.,
Identification of hydroxylic compounds and their derivatives by gas chromatography,
Chromatographia, 1970, 3, 4, 180-195, https://doi.org/10.1007/BF02269018
. [all data]
Zaikin, 2009
Zaikin, V.G.,
Personal Communication: Retention indices measured during the period 2008 to 2009, 2009. [all data]
Notes
Go To: Top, Phase change data, Gas Chromatography, References
- Symbols used in this document:
ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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