(1R,5S,6R)-2,7,7-Trimethylbicyclo[3.1.1]hept-2-en-6-yl acetate
- Formula: C12H18O2
- Molecular weight: 194.2701
- IUPAC Standard InChIKey: UASZOTVHPVEMQR-UHFFFAOYSA-N
- CAS Registry Number: 67999-48-8
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Stereoisomers:
- Other names: Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, 6-acetate, (1R,5S,6R)-; Bicyclo[3.1.1]hept-2-en-6-ol, 2,7,7-trimethyl-, acetate, (1α,5α,6α)-; cis-Chrysanthenol acetate; cis-Chrysanthenyl acetate; Chrysanthenyl acetate; (Z)-Chrysanthenyl acetate; Chrysanthenyl acetate (cis); cis-Crysanthenyl acetate
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | SLB-5 MS | SLB-5 MS | BP-5 | CP Sil 8 CB |
Column length (m) | 25. | 30. | 30. | 30. | 50. |
Carrier gas | Helium | Helium | Helium | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.32 | 0.32 |
Phase thickness (μm) | 0.17 | 0.25 | 0.25 | 0.25 | 0.25 |
Program | 60 0C (5 min) 4 0C/min -> 220 0C 11 0C/min -> 280 0C | 50 0C 3 0C/min -> 250 0C (1 min) 10 0C/min -> 300 0C (5 min) | not specified | 60C => 4C/min => 150C => 10C/min => 220C | 60C(2min) => 5C/min => 160C(1min) => 10C/min => 250C (5min) |
I | 1265. | 1257. | 1261. | 1260. | 1265. |
Reference | Maggi, Bilek, et al., 2009 | Costa, De Fina, et al., 2008 | Costa, De Fina, et al., 2008 | Hashemi, Abolghasemi, et al., 2007 | Judzentiene and Buzelyte, 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | CP Sil 8 CB | CP Sil 8 CB | HP-5MS | SE-30 |
Column length (m) | 30. | 50. | 50. | 30. | |
Carrier gas | He | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.25 | |
Phase thickness (μm) | 0.1 | 0.25 | 0.25 | ||
Program | 35C => 4C/min => 180C => 10C/min => 250C | 60C(2min) => 5C/min => 160C (1min) => 10C/min => 250C (2min) | 60C(2min) => 5C/min => 160C(1min) => 10C/min => 250C (5min) | 50C(3min) => 3C/min => 150C(10min) => 10C/min => 250C | not specified |
I | 1254. | 1262. | 1262. | 1265. | 1253. |
Reference | Albuquerque, Souza, et al., 2004 | Judpentienë and Mockutë, 2004 | Judpentienë and Mockutë, 2004, 2 | Sahin, Gulluce, et al., 2004 | Vinogradov, 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | Methyl Silicone | CP Sil 5 CB | CP Sil 5 CB | Methyl Silicone |
Column length (m) | 25. | 30. | ||
Carrier gas | He | N2 | ||
Substrate | ||||
Column diameter (mm) | 0.25 | |||
Phase thickness (μm) | ||||
Program | not specified | not specified | not specified | not specified |
I | 1253. | 1248. | 1248. | 1260. |
Reference | Zenkevich, 1999 | Weyerstahl, Marschall, et al., 1997 | Weyerstahl, Marschall, et al., 1997, 2 | Vernin and Merad, 1994 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Maggi, Bilek, et al., 2009
Maggi, F.; Bilek, T.; Lucarini, D.; Papa, F.; Sagratini, G.; Vittori, S.,
Melittis melissophyllum L. subsp. melissophylum (Lamiaceae) from central Italy: A new source of a mushrrom-like flavour,
Food Chem., 2009, 113, 1, 216-221, https://doi.org/10.1016/j.foodchem.2008.07.066
. [all data]
Costa, De Fina, et al., 2008
Costa, R.; De Fina, M.R.; Valentino, M.R.; Rustaiyan, A.; Dugo, P.; Dugo, G.; Mondello, L.,
An investigation on the volatile composition of some Artemisia species from Iran,
Flavour Fragr. J., 2008, 24, 2, 75-82, https://doi.org/10.1002/ffj.1919
. [all data]
Hashemi, Abolghasemi, et al., 2007
Hashemi, P.; Abolghasemi, M.M.; Fakhari, A.R.; Ebrahimi, S.N.; Ahmadi, S.,
Hydrodistillation-Solvent Microextraction and GC-MS Identification of Volatile Components of Artemisia aucheri,
Chromatographia, 2007, 66, 3-4, 283-286, https://doi.org/10.1365/s10337-007-0289-4
. [all data]
Judzentiene and Buzelyte, 2006
Judzentiene, A.; Buzelyte, J.,
Chemical composition of essential oils of Artemisia vulgaris L. (mugwort) from North Lithuania,
Chemija, 2006, 17, 1, 12-15. [all data]
Albuquerque, Souza, et al., 2004
Albuquerque, M.R.J.R.; Souza, E.B.; Lins, M.U.D.S.; Nogueira, N.A.P.; Lemos, T.L.G.; Silveira, E.R.; Pessoa, O.D.L.,
Composition and antimicrobial activity of the essential oil from aerial parts of Baccharis trinervis (Lam.) Pers.,
Arkivoc, 2004, 6, 6, 59-65, https://doi.org/10.3998/ark.5550190.0005.608
. [all data]
Judpentienë and Mockutë, 2004
Judpentienë, A.; Mockutë, D.,
Chemical composition of essential oils produced by pink flower inflorescences of wild Achillea millefolium L.,
Chemija, 2004, 15, 28-32. [all data]
Judpentienë and Mockutë, 2004, 2
Judpentienë, A.; Mockutë, D.,
Chemical composition of essential oils of Artemisia absinthium L. (wormwood) growing wild in Vilnius,
Chemija, 2004, 15, 4, 64-68. [all data]
Sahin, Gulluce, et al., 2004
Sahin, F.; Gulluce, M.; Daferera, D.; Sokmen, A.; Sokmen, M.; Polissiou, M.; Agar, G.; Ozer, H.,
Biological activities of the essential oils and methanol extract of Origanum vulgare ssp. vulgare in the Eastern Anatolia region of Turkey,
Food Control, 2004, 15, 7, 549-557, https://doi.org/10.1016/j.foodcont.2003.08.009
. [all data]
Vinogradov, 2004
Vinogradov, B.A.,
Production, composition, properties and application of essential oils, 2004, retrieved from http://viness.narod.ru. [all data]
Zenkevich, 1999
Zenkevich, I.G.,
Analytical Parameters of Components of essential Oils for their Gas Chromatographic and Chromato-Mass-Spectral Identification. Acetates of Terpene Alcohols,
Rastitelnye Resursy (Plant Resources), 1999, 35, 1, 30-37. [all data]
Weyerstahl, Marschall, et al., 1997
Weyerstahl, P.; Marschall, H.; Schröder, M.; Wahlburg, H.-C.; Kaul, V.K.,
The sesquiterpene fraction of the essential oil of Artemisia laciniata Willd.,
Flavour Fragr. J., 1997, 12, 5, 315-325, https://doi.org/10.1002/(SICI)1099-1026(199709/10)12:5<315::AID-FFJ662>3.0.CO;2-Q
. [all data]
Weyerstahl, Marschall, et al., 1997, 2
Weyerstahl, P.; Marschall, H.; Seelmann, I.; Rustaiyan, A.,
Constituents of the essential oil of Achillea eriophora DC,
Flavour Fragr. J., 1997, 12, 2, 71-78, https://doi.org/10.1002/(SICI)1099-1026(199703)12:2<71::AID-FFJ620>3.0.CO;2-E
. [all data]
Vernin and Merad, 1994
Vernin, G.; Merad, L.O.,
Mass Spectra and Kovats Indices of Some New cis-Chrysanthenyl Esters Found in the Essential Oil of Artemisia herba alba from Algeria,
J. Essent. Oil Res., 1994, 6, 4, 437-448, https://doi.org/10.1080/10412905.1994.9698419
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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