6β-Hydroxymethandienone, 2TMS derivative
- Formula: C26H44O3Si2
- Molecular weight: 460.7968
- IUPAC Standard InChI: InChI=1S/C26H44O3Si2/c1-24-13-10-18(27)16-22(24)23(28-30(4,5)6)17-19-20(24)11-14-25(2)21(19)12-15-26(25,3)29-31(7,8)9/h10,13,16,19-21,23H,11-12,14-15,17H2,1-9H3
- IUPAC Standard InChIKey: RAKGZQRFODNUHY-UHFFFAOYSA-N
- CAS Registry Number: 67896-65-5
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: 17α-Methyl-6β,17β-dihydroxy-1,4-androstadien-3-one, bis(trimethylsilyl); 17-Methyl-6,17-bis[(trimethylsilyl)oxy]androsta-1,4-dien-3-one, (6β,17β)-; 6-β-Hydroxymetandienone, per-TMS; 6β-Hydroxy-Methandienone, bis-TMS; 6B-Hydroxymetandienone (Androst-1,4-dien-17A-methyl-6B,17B-diol-3-one), TMS; Hydrastine, bis(trimethylsilyl) ether
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | S.Rendic ET AL., J. Chrom., B, 735,73,(1999) |
| NIST MS number | 308741 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-54 | 2919. | Schänzer, Opfermann, et al., 1992 | 5. K/min; Column length: 17. m; Phase thickness: 0.33 μm; Tstart: 200. C; Tend: 320. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2915. | Bowers, 1996 | 30. m/0.25 mm/0.25 μm, Helium; Program: 170 0C 20 0C/min -> 260 0C 2.7 0C/min -> 305 0C 20 0C/min -> 320 0C |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Schänzer, Opfermann, et al., 1992
Schänzer, W.; Opfermann, G.; Donike, M.,
17-Epimerization of 17α-methyl anabolic steroids in humans: metabolism and synthesis of 17α-hydroxy-17β-methyl steroids,
Steroids, 1992, 57, 11, 537-550, https://doi.org/10.1016/0039-128X(92)90023-3
. [all data]
Bowers, 1996
Bowers, L.D.,
Separation and confirmation of anabolic steroids with quadrupole ion trap tandem mass spectrometry,
J. Chromatogr. B, 1996, 687, 1, 69-78, https://doi.org/10.1016/S0378-4347(96)00231-9
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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