Trichloromethane

• Formula: CHCl₃
• Molecular weight: 119.378
• IUPAC Standard InChI: InChI=1S/CHCl3/c2-1(3)4/h1H Copy

  
• IUPAC Standard InChIKey: HEDRZPFGACZZDS-UHFFFAOYSA-N Copy
• CAS Registry Number: 67-66-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Isotopologues:
  • Chloroform, deutero-
  • Chloroform, deutero-
  • Methane-d, trichloro-
• Other names: Chloroform; Freon 20; Methane, trichloro-; R 20; Trichloroform; CHCl3; Formyl trichloride; Methane trichloride; Methenyl trichloride; Methyl trichloride; Chloroforme; Cloroformio; NCI-C02686; R 20 (refrigerant); Trichloormethaan; Trichlormethan; Triclorometano; Rcra waste number U044; UN 1888; NSC 77361; F 20
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
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  • Gas Chromatography
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Sevcik, Boublik, et al., 1978
Sevcik, M.; Boublik, T.; Biros, J., Excess thermodynamic functions in the cyclopentane(1) + chloroform(2) system at 298.15 k, Collect. Czech. Chem. Commun., 1978, 43, 2242-9. [all data]

Ezhov, Golovko, et al., 1976
Ezhov, V.S.; Golovko, S.N.; Guseinov, E.M., Determination of the equilibrium characteristics of vapor-liquid and liquid-liquid systems applicable to products of the oxidative ammonolysis of toluene and alpha- and beta-picolines, Khim.-Farm. Zh., 1976, 10, 10, 77. [all data]

Abramov, Mirzayan, et al., 1972
Abramov, E.V.; Mirzayan, A.S.; Fedorova, V.I., Heats of formation of ternary systems 1. the acetic acid + chloroform system, Izv. Akad. Nauk Kaz. SSR, Ser. Khim., 1972, 22, 4, 26. [all data]

Boublik and Aim, 1972
Boublik, T.; Aim, K., Heats of Vaporization of Simple Non-spherical Molecule Compounds, Collect. Czech. Chem. Commun., 1972, 37, 3513. [all data]

Kirby and Van Winkle, 1970
Kirby, C.E.; Van Winkle, M., Vapor-liquid equilibria 2,3-dimethylbutane + methanol and 2,3- dimethylbutane + methanol + chloroform systems, J. Chem. Eng. Data, 1970, 15, 177-82. [all data]

Willock and Van Winkle, 1970
Willock, J.M.; Van Winkle, M., Binary and Ternary Vapor-Liquid Equilibria of Methano-Acetone-2,3-Dimethyl- butane, J. Chem. Eng. Data, 1970, 15, 281. [all data]

Garrett and Van Winkle, 1969
Garrett, G.R.; Van Winkle, M., Vapor-Liquid Equilibria of the Ternary System Acetone-Chloroform-2,3- Dimethylbutane, J. Chem. Eng. Data, 1969, 14, 302. [all data]

Hudson and Van Winkle, 1969
Hudson, J.W.; Van Winkle, M., Multicomponent Vapor-Liquid Equilibria in Systems of Mixed Positive and Negative Deviations, J. Chem. Eng. Data, 1969, 14, 310-8. [all data]

Findlay, Keniry, et al., 1967
Findlay, T.J.V.; Keniry, J.S.; Kidman, A.D.; Pickles, V.A., Calorimetric and N.M.R. studies of hydrogen bonding involving C-H bonds, Trans. Faraday Soc., 1967, 63, 846. [all data]

McConnell and Van Winkle, 1967
McConnell, C.G.; Van Winkle, M., Vapor-Liquid Equilibria in the Acetone-2,3-Dimethylbutane and Chloroform-2,3-Dimethylbutane Systems, J. Chem. Eng. Data, 1967, 12, 430-2. [all data]

Kudryavtseva and Susarev, 1963
Kudryavtseva, L.S.; Susarev, M.P., Liquid-vapor equilibrium in the systems acetone-hexane and hexane-ethyl alcohol at 35, 45, and 55 deg. and 760 mm of Hg., Zh. Prikl. Khim. (Leningrad), 1963, 36, 1471. [all data]

Kudryavtseva and Susarev, 1963, 2
Kudryavtseva, L.S.; Susarev, M.P., Liquid-vapor equilibrium in the ethyl alcohol + chloroform + hexane system at temperatures of 55, 45, and 35 c and a pressure of 760 mm hg, Zh. Prikl. Khim. (Leningrad), 1963, 36, 2025-2030. [all data]

Nagata, 1962
Nagata, I., Vapor-Liquid Equilibriumat Atmospheric Pressure for the Ternary System Methyl Acetate-Chloroform-Benzene, J. Chem. Eng. Data, 1962, 7, 360. [all data]

Nagata, 1962, 2
Nagata, I., Isobaric Vapor-Liquid Equilibria for the Ternary System Chloroform- Methanol-Ethyl Acetate, J. Chem. Eng. Data, 1962, 7, 367-73. [all data]

Conti, Othmer, et al., 1960
Conti, J.J.; Othmer, D.F.; Gilmont, R., Composition of Vapors from Boiling Binary Solutions. Systems Containing Formic Acid, Acetic Acid, Water and Chloroform, J. Chem. Eng. Data, 1960, 5, 301. [all data]

Gjaldbaek and Andersen, 1954
Gjaldbaek, J. Chr.; Andersen, E.K., The Solubility of Carbon Dioxide, Oxygen, Carbon Monoxide and Nitrogen in Polar Solvents, Acta Chem. Scand., 1954, 8, 1398. [all data]

Newitt and Weale, 1951
Newitt, D.M.; Weale, K.E., Pressure-volume-temperature relations in liquids and liquid mixtures: II the compression isotherms of some organic liquids up to 1000 atmospheres, and the compressions of some aqueous and nonaqueous, J. Chem. Soc., 1951, 1951, 3092-8. [all data]

Sauer and Hadsell, 1948
Sauer, R.O.; Hadsell, E.M., Azeotropes of Trimethylchlorosilane and Silicon Tetrachloride, J. Am. Chem. Soc., 1948, 70, 4258-9. [all data]

Ewell and Welch, 1941
Ewell, R.H.; Welch, L.M., Maximum Boiling Mixtures of chloroparaffins with Donor Liquids, J. Am. Chem. Soc., 1941, 63, 2475. [all data]

Maryott, Hobbs, et al., 1941
Maryott, A.A.; Hobbs, M.E.; Gross, P.M., Bond Moment Additivity and the Electric Moments of Some Halogenated Hydrocarbons, J. Am. Chem. Soc., 1941, 63, 659. [all data]

Reinders and De Minjer, 1940
Reinders, W.; De Minjer, C.H., Vapour-liquid equilibria in the ternary systems. chloroform + benzene, Recl. Trav. Chim. Pays-Bas, 1940, 59, 369-91. [all data]

Stull, 1937
Stull, D.R., A Semi-micro Calorimeter for Measuring Heat Capacities at Low Temp., J. Am. Chem. Soc., 1937, 59, 2726. [all data]

Earp and Glasstone, 1935
Earp, D.P.; Glasstone, S., Dielectric polarisation and molecular-compound formation in solution, J. Chem. Soc., 1935, 1935, 1709. [all data]

Stearn and Smyth, 1934
Stearn, A.E.; Smyth, C.P., The effect of solvent upon the moment of a molecule containing movable dipoles, J. Am. Chem. Soc., 1934, 56, 1667-70. [all data]

Gross and Saylor, 1931
Gross, P.M.; Saylor, J.H., The Solubilities of Certain Slightly Soluble Org. Compounds in Water, J. Am. Chem. Soc., 1931, 53, 1744. [all data]

Trew and Spencer, 1931
Trew, V.C.G.; Spencer, J.F., The Magnetic Susceptibility of Binary Systems of Organic Liquids, Proc. R. Soc. London, A, 1931, 131, 209. [all data]

Lecat, 1927
Lecat, M., New binary azeotropes: 7th list, Ann. Soc. Sci. Bruxelles, Ser. B, 1927, 47, 108-14. [all data]

Mathews, 1926
Mathews, J.H., The Accurate Measurement of Heats of Vaporization of Liquids, J. Am. Chem. Soc., 1926, 48, 562. [all data]

Williams and Daniels, 1925
Williams, J.W.; Daniels, F., The specific heats of binary mixtures, J. Am. Chem. Soc., 1925, 47, 1490-1503. [all data]

Williams and Daniels, 1924
Williams, J.W.; Daniels, F., The Specific Heats of Certain Organic Liquids at Elevated Temperatures, J. Am. Chem. Soc., 1924, 46, 903-17. [all data]

Grimm and Patrick, 1923
Grimm, F.V.; Patrick, W.A., The Dielectric Constastants of Organic Liquids at the Boilin Point, J. Am. Chem. Soc., 1923, 45, 2794. [all data]

Herz and Neukirch, 1923
Herz, W.; Neukirch, E., On Knowldge of the Critical State, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1923, 104, 433-50. [all data]

Paul and Schantz, 1919
Paul, T.; Schantz, K., The boiling point as indicator of purity and a new apparatus for its determination without thermometer correction., Arch. Pharm. (Weinheim, Ger.), 1919, 257, 87. [all data]

Timmermans, 1911
Timmermans, J., Researches on the freezing point of organic liquid compounds, Bull. Soc. Chim. Belg., 1911, 25, 300. [all data]

Timmermans, 1910
Timmermans, J., The Purification and Physical Constants of Several Organic Liquids, Bull. Soc. Chim. Belg., 1910, 24, 244. [all data]

Linebarger, 1896
Linebarger, C.E., Am. Chem. J., 1896, 18, 429. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

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