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Isopropyl Alcohol

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H7O- + Hydrogen cation = Isopropyl Alcohol

By formula: C3H7O- + H+ = C3H8O

Quantity Value Units Method Reference Comment
Deltar1569. ± 4.2kJ/molD-EARamond, Davico, et al., 2000gas phase; B
Deltar1571. ± 8.8kJ/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Deltar1576. ± 4.2kJ/molCIDTDeTuri and Ervin, 1999gas phase; B
Deltar1572. ± 8.4kJ/molCIDCHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B
Quantity Value Units Method Reference Comment
Deltar1542. ± 4.6kJ/molH-TSRamond, Davico, et al., 2000gas phase; B
Deltar1543. ± 8.4kJ/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Deltar1544. ± 8.8kJ/molH-TSHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B

Chlorine anion + Isopropyl Alcohol = (Chlorine anion bullet Isopropyl Alcohol)

By formula: Cl- + C3H8O = (Cl- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar81.17 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar76.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar47.36kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar45.61kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

C2H7O+ + Isopropyl Alcohol = (C2H7O+ bullet Isopropyl Alcohol)

By formula: C2H7O+ + C3H8O = (C2H7O+ bullet C3H8O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar133.kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KN/ABomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar96.7kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M

C3H9O+ + Isopropyl Alcohol = (C3H9O+ bullet Isopropyl Alcohol)

By formula: C3H9O+ + C3H8O = (C3H9O+ bullet C3H8O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar133.kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KN/ABomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar96.7kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M

C4H11O+ + Isopropyl Alcohol = (C4H11O+ bullet Isopropyl Alcohol)

By formula: C4H11O+ + C3H8O = (C4H11O+ bullet C3H8O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar128.kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar118.J/mol*KN/ABomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar92.5kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M

C4H11O+ + Isopropyl Alcohol = (C4H11O+ bullet Isopropyl Alcohol)

By formula: C4H11O+ + C3H8O = (C4H11O+ bullet C3H8O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar134.kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KN/ABomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar99.6kJ/molICRBomse and Beauchamp, 1981gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M

CN- + Isopropyl Alcohol = (CN- bullet Isopropyl Alcohol)

By formula: CN- + C3H8O = (CN- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar76. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar104.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar37.7 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar44.8 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

Fluorine anion + Isopropyl Alcohol = (Fluorine anion bullet Isopropyl Alcohol)

By formula: F- + C3H8O = (F- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar140.2 ± 2.9kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar135. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Deltar139. ± 9.2kJ/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar107.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar103. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

C3H9Si+ + Isopropyl Alcohol = (C3H9Si+ bullet Isopropyl Alcohol)

By formula: C3H9Si+ + C3H8O = (C3H9Si+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar184.kJ/molPHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar129.J/mol*KN/AWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
123.468.PHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

(Chlorine anion bullet 2Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 3Isopropyl Alcohol)

By formula: (Cl- bullet 2C3H8O) + C3H8O = (Cl- bullet 3C3H8O)

Quantity Value Units Method Reference Comment
Deltar62.3 ± 2.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar52.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar20. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 2Isopropyl Alcohol)

By formula: (Cl- bullet C3H8O) + C3H8O = (Cl- bullet 2C3H8O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar65.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 8Isopropyl Alcohol)

By formula: (Cl- bullet 7C3H8O) + C3H8O = (Cl- bullet 8C3H8O)

Quantity Value Units Method Reference Comment
Deltar45.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Iodide + Isopropyl Alcohol = (Iodide bullet Isopropyl Alcohol)

By formula: I- + C3H8O = (I- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar54.81 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar51.0 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Hydrogen + Acetone = Isopropyl Alcohol

By formula: H2 + C3H6O = C3H8O

Quantity Value Units Method Reference Comment
Deltar-68.74 ± 0.42kJ/molCmWiberg, Crocker, et al., 1991liquid phase; ALS
Deltar-55.23kJ/molEqkBuckley and Herington, 1965gas phase; ALS
Deltar-55.40 ± 0.42kJ/molChydDolliver, Gresham, et al., 1938gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -56.1 ± 0.4 kJ/mol; At 355 °K; ALS

Bromine anion + Isopropyl Alcohol = C3H8BrO-

By formula: Br- + C3H8O = C3H8BrO-

Quantity Value Units Method Reference Comment
Deltar60.25 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar34.9kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar38. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Sodium ion (1+) + Isopropyl Alcohol = (Sodium ion (1+) bullet Isopropyl Alcohol)

By formula: Na+ + C3H8O = (Na+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar113. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000RCD
Deltar113. ± 4.6kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
85.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

(Chlorine anion bullet 3Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 4Isopropyl Alcohol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 5Isopropyl Alcohol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 6Isopropyl Alcohol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar47.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 7Isopropyl Alcohol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

MeS anion + Isopropyl Alcohol = (MeS anion bullet Isopropyl Alcohol)

By formula: CH3S- + C3H8O = (CH3S- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar71.55 ± 0.84kJ/molTDAsSieck and Meot-ner, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar42.7 ± 3.3kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

Fluorine anion + 2Isopropyl Alcohol = C6H16FO2-

By formula: F- + 2C3H8O = C6H16FO2-

Quantity Value Units Method Reference Comment
Deltar87.03 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar55.48kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

thiophenoxide anion + Isopropyl Alcohol = C9H13OS-

By formula: C6H5S- + C3H8O = C9H13OS-

Quantity Value Units Method Reference Comment
Deltar62.76 ± 0.42kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.5 ± 1.7kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

Fluorine anion + 3Isopropyl Alcohol = C9H24FO3-

By formula: F- + 3C3H8O = C9H24FO3-

Quantity Value Units Method Reference Comment
Deltar73.64 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar35.0kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Iodide + 2Isopropyl Alcohol = C6H16IO2-

By formula: I- + 2C3H8O = C6H16IO2-

Quantity Value Units Method Reference Comment
Deltar46.0 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar19.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 2Isopropyl Alcohol = C6H16BrO2-

By formula: Br- + 2C3H8O = C6H16BrO2-

Quantity Value Units Method Reference Comment
Deltar51.46 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar22.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Iodide + 3Isopropyl Alcohol = C9H24IO3-

By formula: I- + 3C3H8O = C9H24IO3-

Quantity Value Units Method Reference Comment
Deltar39.7 ± 2.9kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar14.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

1-Propene, 2-methyl- + Isopropyl Alcohol = Propane, 2-methyl-2-(1-methylethoxy)-

By formula: C4H8 + C3H8O = C7H16O

Quantity Value Units Method Reference Comment
Deltar-22.9 ± 1.3kJ/molEqkCalderon, Tejero, et al., 1997liquid phase; ALS
Deltar-21.7 ± 1.6kJ/molCmSola, Pericas, et al., 1997liquid phase; ALS

Isopropyl Alcohol = Hydrogen + Acetone

By formula: C3H8O = H2 + C3H6O

Quantity Value Units Method Reference Comment
Deltar55.23kJ/molEqkBuckley and Herington, 1965gas phase; ALS
Deltar56.543kJ/molEqkKolb and Burwell, 1945gas phase; ALS

Fluorine anion + Isopropyl Alcohol = C3H7D8FO-

By formula: F- + C3H8O = C3H7D8FO-

Quantity Value Units Method Reference Comment
Deltar102. ± 8.4kJ/molIMREWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B

Magnesium ion (1+) + Isopropyl Alcohol = (Magnesium ion (1+) bullet Isopropyl Alcohol)

By formula: Mg+ + C3H8O = (Mg+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar270. ± 20.kJ/molICROperti, Tews, et al., 1988gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M

Isopropyl acetate + Water = Acetic acid + Isopropyl Alcohol

By formula: C5H10O2 + H2O = C2H4O2 + C3H8O

Quantity Value Units Method Reference Comment
Deltar2.3 ± 0.2kJ/molCmWadso, 1958liquid phase; Heat of Hydrolysis; ALS

Isopropyl Alcohol + Chloral = 2,2,2-trichloro-1-isopropoxyethanol

By formula: C3H8O + C2HCl3O = 2,2,2-trichloro-1-isopropoxyethanol

Quantity Value Units Method Reference Comment
Deltar-41.6kJ/molEqkJensen and Pedersen, 1971liquid phase; solvent: Heptane; ALS

Cyclohexanol + Acetone = Cyclohexanone + Isopropyl Alcohol

By formula: C6H12O + C3H6O = C6H10O + C3H8O

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.9kJ/molEqkFedoseenko, Yursha, et al., 1983gas phase; At 503 K; ALS

Isopropyl Alcohol + Ethene, 1,1-dichloro-2,2-difluoro- = C5H8Cl2F2O

By formula: C3H8O + C2Cl2F2 = C5H8Cl2F2O

Quantity Value Units Method Reference Comment
Deltar-183. ± 1.kJ/molEqkKennedy, Lacher, et al., 1969gas phase; ALS

Cyclohexanone + Isopropyl Alcohol = Cyclohexanol + Acetone

By formula: C6H10O + C3H8O = C6H12O + C3H6O

Quantity Value Units Method Reference Comment
Deltar-9.9 ± 1.9kJ/molEqkKabo, Yursha, et al., 1988gas phase; ALS

Isopropyl Alcohol + Nitric acid = Nitric acid, 1-methylethyl ester + Water

By formula: C3H8O + HNO3 = C3H7NO3 + H2O

Quantity Value Units Method Reference Comment
Deltar-23.4kJ/molEqkRubtsov, 1986liquid phase; ALS

Ketene + Isopropyl Alcohol = Isopropyl acetate

By formula: C2H2O + C3H8O = C5H10O2

Quantity Value Units Method Reference Comment
Deltar-150.2kJ/molCmRice and Greenberg, 1934liquid phase; ALS

Lithium ion (1+) + Isopropyl Alcohol = (Lithium ion (1+) bullet Isopropyl Alcohol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar173. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ramond, Davico, et al., 2000
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C., Vibronic structure of alkoxy radicals via photoelectron spectroscopy, J. Chem. Phys., 2000, 112, 3, 1158-1169, https://doi.org/10.1063/1.480767 . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

DeTuri and Ervin, 1999
DeTuri, V.F.; Ervin, K.M., Competitive threshold collision-induced dissociation: Gas-phase acidities and bond dissociation energies for a series of alcohols, J. Phys. Chem. A, 1999, 103, 35, 6911-6920, https://doi.org/10.1021/jp991459m . [all data]

Haas and Harrison, 1993
Haas, M.J.; Harrison, A.G., The Fragmentation of Proton-Bound Cluster Ions and the Gas-Phase Acidities of Alcohols, Int. J. Mass Spectrom. Ion Proc., 1993, 124, 2, 115, https://doi.org/10.1016/0168-1176(93)80003-W . [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. An experimental investigation of the interaction between chloride ion and bronsted acids from ICR chloride exchange equilibria, J. Am. Chem. Soc., 1984, 106, 517. [all data]

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Notes

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