Methyl Alcohol
- Formula: CH4O
- Molecular weight: 32.0419
- IUPAC Standard InChI: InChI=1S/CH4O/c1-2/h2H,1H3
- IUPAC Standard InChIKey: OKKJLVBELUTLKV-UHFFFAOYSA-N
- CAS Registry Number: 67-56-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Methanol; Carbinol; Methyl hydroxide; Methylol; Monohydroxymethane; Wood alcohol; CH3OH; Colonial spirit; Columbian spirit; Hydroxymethane; Wood naphtha; Alcool methylique; Alcool metilico; Columbian spirits; Metanolo; Methylalkohol; Metylowy alkohol; Pyroxylic spirit; Wood spirit; Rcra waste number U154; UN 1230; Pyro alcohol; Spirit of wood; Bieleski's solution; NSC 85232
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- Other data available:
- Phase change data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300
- Henry's Law data
- Gas phase ion energetics data
- Ion clustering data
- Mass spectrum (electron ionization)
- Gas Chromatography
- Fluid Properties
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -205. ± 10. | kJ/mol | AVG | N/A | Average of 9 values; Individual data points |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°gas | -763.68 ± 0.20 | kJ/mol | Cm | Rossini, 1932 | Flame Calorimetry; Corresponding ΔfHºgas = -201.49 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Constant pressure heat capacity of gas
| Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 34.00 | 50. | Thermodynamics Research Center, 1997 | p=1 bar. Recommended entropies and heat capacities are in good agreement with other statistically calculated values [ Ivash E.V., 1955, Zhuravlev E.Z., 1959, Chen S.S., 1977, Chao J., 1986, Gurvich, Veyts, et al., 1989]. Please also see Chao J., 1986, 2.; GT |
| 36.95 | 100. | ||
| 38.64 | 150. | ||
| 39.71 | 200. | ||
| 42.59 | 273.15 | ||
| 44.06 ± 0.03 | 298.15 | ||
| 44.17 | 300. | ||
| 51.63 | 400. | ||
| 59.70 | 500. | ||
| 67.19 | 600. | ||
| 73.86 | 700. | ||
| 79.76 | 800. | ||
| 84.95 | 900. | ||
| 89.54 | 1000. | ||
| 93.57 | 1100. | ||
| 97.12 | 1200. | ||
| 100.24 | 1300. | ||
| 102.98 | 1400. | ||
| 105.40 | 1500. | ||
| 110.2 | 1750. | ||
| 113.8 | 2000. | ||
| 116.5 | 2250. | ||
| 118.6 | 2500. | ||
| 120. | 2750. | ||
| 121. | 3000. |
Constant pressure heat capacity of gas
| Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 42.4 ± 1.3 | 279. | Stromsoe E., 1970 | Heat capacity at 279 K was obtained by thermal conductivity [ Halford J.O., 1957]. Vapor heat capacities from calorimetric measurements [ De Vries T., 1941] were converted to the ideal gas heat capacities by corrections for the gas imperfection effects [ Chen S.S., 1977, Chao J., 1986, 2]. Ideal gas heat capacities are given by [ Stromsoe E., 1970] as a linear function Cp=f1*(a+bT). This expression approximates the experimental values with the average deviation of 1.17 J/mol*K. The accuracy of the experimental heat capacities [ Stromsoe E., 1970] is estimated as less than 0.3%. Please also see De Vries T., 1941, Weltner W., 1951, Halford J.O., 1957.; GT |
| 48.0 ± 1.3 | 345.6 | ||
| 46.8 ± 1.2 | 347.35 | ||
| 46.1 ± 1.3 | 349.65 | ||
| 47.6 ± 1.2 | 356.55 | ||
| 46.7 ± 1.3 | 358.15 | ||
| 48.2 ± 1.3 | 358.85 | ||
| 48.8 ± 1.3 | 359.85 | ||
| 50.3 ± 1.3 | 368.15 | ||
| 49.0 ± 1.2 | 373.35 | ||
| 51.3 ± 1.3 | 382.15 | ||
| 51.1 ± 1.2 | 398.95 | ||
| 52.3 ± 1.3 | 401.15 | ||
| 51.3 ± 1.2 | 401.35 | ||
| 52.01 ± 0.42 | 403.2 | ||
| 53.2 ± 1.3 | 420.15 | ||
| 53.9 ± 1.2 | 431.45 | ||
| 54.8 ± 1.2 | 442.15 | ||
| 55.9 ± 1.3 | 442.65 | ||
| 56.0 ± 1.2 | 457.35 | ||
| 57.20 ± 0.42 | 464.0 | ||
| 57.8 ± 1.2 | 477.75 | ||
| 58.4 ± 1.2 | 485.05 | ||
| 59.5 ± 1.2 | 498.95 | ||
| 60.4 ± 1.3 | 521.2 | ||
| 61.4 ± 1.2 | 521.35 | ||
| 64.3 ± 1.2 | 555.95 | ||
| 66.4 ± 1.2 | 581.35 | ||
| 66.8 ± 1.2 | 585.35 |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -238.4 | kJ/mol | Ccr | Baroody and Carpenter, 1972 | ALS |
| ΔfH°liquid | -239.5 ± 0.2 | kJ/mol | Ccb | Chao and Rossini, 1965 | see Rossini, 1934; ALS |
| ΔfH°liquid | -238.9 ± 3.6 | kJ/mol | Ccb | Green, 1960 | Reanalyzed by Cox and Pilcher, 1970, Original value = -238.5 ± 0.2 kJ/mol; ALS |
| ΔfH°liquid | -250.6 | kJ/mol | Ccb | Parks, 1925 | ALS |
| ΔfH°liquid | -251.3 ± 5.0 | kJ/mol | Ccb | Richards and Davis, 1920 | DRB |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -725.7 ± 0.1 | kJ/mol | Ccb | Chao and Rossini, 1965 | see Rossini, 1934; Corresponding ΔfHºliquid = -239.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -726.5 ± 0.2 | kJ/mol | Ccb | Green, 1960 | Corresponding ΔfHºliquid = -238.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -726.34 ± 0.20 | kJ/mol | Ccb | Rossini, 1931 | Corresponding ΔfHºliquid = -238.83 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -715.05 | kJ/mol | Ccb | Parks, 1925 | Corresponding ΔfHºliquid = -250.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| ΔcH°liquid | -713.83 | kJ/mol | Ccb | Richards and Davis, 1920 | At 291 K; Corresponding ΔfHºliquid = -251.34 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid | 127.19 | J/mol*K | N/A | Carlson and Westrum, 1971 | DH |
| S°liquid | 126.8 | J/mol*K | N/A | Kelley, 1929 | DH |
| S°liquid | 129.7 | J/mol*K | N/A | Parks, Kelley, et al., 1929 | Extrapolation below 90 K, 34.3 J/mol*K. Revision of previous data.; DH |
| S°liquid | 136.4 | J/mol*K | N/A | Parks, 1925 | Extrapolation below 90 K, 40.75 J/mol*K.; DH |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid,1 bar | 1.117 | J/mol*K | N/A | Ahlberg, Blanchard, et al., 1937 | DH |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 79.5 | 298.15 | Filatov and Afanas'ev, 1992 | DH |
| 81.11 | 298.15 | Khasanshin and Zykova, 1989 | T = 175 to 338 K. Unsmoothed experimental datum.; DH |
| 80.24 | 298.15 | Andreoli-Ball, Patterson, et al., 1988 | DH |
| 80.35 | 298.15 | Okano, Ogawa, et al., 1988 | DH |
| 81.0 | 298.15 | Lankford and Criss, 1987 | DH |
| 81.32 | 298. | Korolev, Kukharenko, et al., 1986 | DH |
| 80.28 | 298.15 | Ogawa and Murakami, 1986 | DH |
| 81.56 | 298.15 | Tanaka, Toyama, et al., 1986 | DH |
| 80.22 | 298.15 | Costas and Patterson, 1985 | T = 298.15, 313.15 K.; DH |
| 81.47 | 298.15 | Zegers and Somsen, 1984 | DH |
| 78.90 | 288.15 | Benson and D'Arcy, 1982 | DH |
| 81.92 | 298.15 | Villamanan, Casanova, et al., 1982 | DH |
| 80.8 | 293.15 | Atalla, El-Sharkawy, et al., 1981 | DH |
| 81.13 | 298.15 | Carlson and Westrum, 1971 | T = 5 to 332 K.; DH |
| 83.7 | 298. | Deshpande and Bhatagadde, 1971 | T = 298 to 318 K.; DH |
| 85.8 | 313.2 | Paz Andrade, Paz, et al., 1970 | DH |
| 85.8 | 298.2 | Katayama, 1962 | T = 10 to 60°C.; DH |
| 80.8 | 311. | Swietoslawski and Zielenkiewicz, 1960 | Mean value 21 to 56°C.; DH |
| 86.2 | 323. | Hough, Mason, et al., 1950 | T = 323 to 353 K.; DH |
| 75.77 | 270. | Staveley and Gupta, 1949 | T = 90 to 270 K.; DH |
| 86.6 | 300.8 | Phillip, 1939 | DH |
| 83.56 | 313.15 | Fiock, Ginnings, et al., 1931 | T = 40 to 110°C.; DH |
| 79.9 | 292.0 | Kelley, 1929 | T = 16 to 293 K. Value is unsmoothed experimental datum.; DH |
| 78.2 | 270. | Mitsukuri and Hara, 1929 | T = 190 to 270 K.; DH |
| 79.9 | 290.1 | Parks, 1925 | T = 89 to 290 K. Value is unsmoothed experimental datum.; DH |
| 83.3 | 298. | von Reis, 1881 | T = 288 to 335 K.; DH |
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 68.39 | 120. | Sugisaki, Suga, et al., 1968 | glass phase; T = 20 to 120 K.; DH |
| 5.40 | 20.5 | Ahlberg, Blanchard, et al., 1937 | T = 5 to 28 K.; DH |
| 105. | 173. | Maass and Walbauer, 1925 | T = 93 to 173 K.; DH |
IR Spectrum
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes
Data compiled by: Coblentz Society, Inc.
- GAS (70 mmHg, N2 ADDED, TOTAL PRESSURE 600 mmHg); DOW KBr FOREPRISM-GRATING; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 2 cm-1 resolution
- GAS (VAPOR); PERKIN-ELMER 21 (GRATING); DIGITIZED BY NIST FROM HARD COPY; 4 cm-1 resolution
- SOLUTION (2% IN CCl4 FOR 3800-1330, 2% IN CS2 FOR 1330-400 CM-1) VS SOLVENT; DOW KBr FOREPRISM-GRATING; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 4 cm-1 resolution
Data compiled by: Pamela M. Chu, Franklin R. Guenther, George C. Rhoderick, and Walter J. Lafferty
- gas; IFS66V (Bruker); 3-Term B-H Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm-1 resolution - gas; IFS66V (Bruker); Boxcar Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm-1 resolution - gas; IFS66V (Bruker); Happ Genzel Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm-1 resolution - gas; IFS66V (Bruker); NB Strong Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm-1 resolution - gas; IFS66V (Bruker); Triangular Apodization
0.1250, 0.2410, 0.4820, 0.9640, 1.9290 cm-1 resolution
Vibrational and/or electronic energy levels
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Gas Symmetry: Cs Symmetry Number σ = 1
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a' | 1 | OH str | 3681 | A | 3681 M | gas | ||||
| a' | 2 | CH3 d-str | 3000 | C | 3000 M | gas | ||||
| a' | 3 | CH3 s-str | 2844 | A | 2844 S | gas | ||||
| a' | 4 | CH3 d-deform | 1477 | B | 1477 M | gas | OV(ν10) | |||
| a' | 5 | CH3 s-deform | 1455 | A | 1455 M | gas | ||||
| a' | 6 | OH bend | 1345 | B | 1345 S | gas | ||||
| a' | 7 | CH3 rock | 1060 | D | 1060 W | gas | OV(ν8) | |||
| a' | 8 | CO str | 1033 | A | 1033 VS | gas | 1032 | gas | ||
| a | 9 | CH3 d-str | 2960 | C | 2960 S | gas | 2955 | gas | ||
| a | 10 | CH3 d-deform | 1477 | B | 1477 M | gas | OV(ν4) | |||
| a | 11 | CH3 rock | 1165 | C | 1165 | liq. | ||||
| a | 12 | Torsion | 295 | A | 80~300 | gas | ?/? Value of ν12 is undefined because of large coupling between internal & overall rotations. | |||
| a | 12 | Torsion | 200 | E | 80~300 | gas | ?/? Value of ν12 is undefined because of large coupling between internal & overall rotations. | |||
Source: Shimanouchi, 1972
Liquid Symmetry: Cs Symmetry Number σ = 1
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a' | 1 | OH str | 3328 | D | 3328 vb | liq. | 3270-3480 | liq. | ||
| a' | 2 | CH3 d-str | 2980 | C | 2980 M | liq. | 2993 | liq. | ||
| a' | 3 | CH3 s-str | 2834 | C | 2834 S | liq. | 2834 | liq. | ||
| a' | 4 | CH3 d-deform | 1480 | C | 1480 M | liq. | 1464 | liq. | OV(ν10) | |
| a' | 5 | CH3 s-deform | 1450 | C | 1450 M | liq. | ||||
| a' | 6 | OH bend | 1418 | C | 1418 M b | liq. | ||||
| a' | 7 | CH3 rock | 1115 | C | 1115 M | liq. | 1107 | liq. | ||
| a' | 8 | CO str | 1030 | C | 1030 VS | liq. | 1033 | liq. | ||
| a | 9 | CH3 d-str | 2946 | C | 2946 S | liq. | 2940 | liq. | ||
| a | 10 | CH3 d-deform | 1480 | C | 1480 M | liq. | 1464 | liq. | OV(ν4) | |
| a | 11 | CH3 rock | 1165 | C | 1165 | liq. | ||||
| a | 12 | Torsion | 655 | D | 655 vb | liq. | ||||
Source: Shimanouchi, 1972
Notes
| VS | Very strong |
| S | Strong |
| M | Medium |
| W | Weak |
| b | Broad |
| vb | Very broad |
| OV | Overlapped by band indicated in parentheses. |
| A | 0~1 cm-1 uncertainty |
| B | 1~3 cm-1 uncertainty |
| C | 3~6 cm-1 uncertainty |
| D | 6~15 cm-1 uncertainty |
| E | 15~30 cm-1 uncertainty |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, IR Spectrum, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rossini, 1932
Rossini, F.D.,
The heats of combustion of methyl and ethyl alcohols,
J. Res. NBS, 1932, 8, 119-139. [all data]
Thermodynamics Research Center, 1997
Thermodynamics Research Center,
Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]
Ivash E.V., 1955
Ivash E.V.,
Thermodynamic properties of ideal gaseous methanol,
J. Chem. Phys., 1955, 23, 1814-1818. [all data]
Zhuravlev E.Z., 1959
Zhuravlev E.Z.,
Isotopic effect on thermodynamic functions of some organic deuterocompounds in the ideal gas state,
Tr. Khim. i Khim. Tekhnol., 1959, 2, 475-485. [all data]
Chen S.S., 1977
Chen S.S.,
Thermodynamic properties of normal and deuterated methanols,
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Chao J., 1986
Chao J.,
Ideal gas thermodynamic properties of simple alkanols,
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Gurvich, Veyts, et al., 1989
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.,
Thermodynamic Properties of Individual Substances, 4th ed.; Vols. 1 and 2, Hemisphere, New York, 1989. [all data]
Chao J., 1986, 2
Chao J.,
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Stromsoe E.,
Heat capacity of alcohol vapors at atmospheric pressure,
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Halford J.O., 1957
Halford J.O.,
Standard heat capacities of gaseous methanol, ethanol, methane and ethane at 279 K by thermal conductivity,
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De Vries T., 1941
De Vries T.,
The heat capacity of organic vapors. I. Methyl alcohol,
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Weltner W., 1951
Weltner W., Jr.,
Methyl alcohol: the entropy, heat capacity and polymerization equilibria in the vapor, and potential barrier to internal rotation,
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Baroody and Carpenter, 1972
Baroody, E.E.; Carpenter, G.A.,
Heats of formation of propellant compounds (U), Rpt. Naval Ordnance Systems Command Task No. 331-003/067-1/UR2402-001 for Naval Ordance Station, Indian Head, MD, 1972, 1-9. [all data]
Chao and Rossini, 1965
Chao, J.; Rossini, F.D.,
Heats of combustion, formation, and isomerization of nineteen alkanols,
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Rossini, 1934
Rossini, F.D.,
Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages,
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Green, 1960
Green, J.H.S.,
Revision of the values of the heats of formation of normal alcohols,
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Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
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Parks, 1925
Parks, G.S.,
Thermal data on organic compounds I. The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols,
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Richards and Davis, 1920
Richards, T.W.; Davis, H.S.,
The heats of combustion of benzene, toluene, aliphatic alcohols, cyclohexanol, and other carbon compounds,
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Rossini, 1931
Rossini, F.D.,
The heat of combustion of methyl alcohol,
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Carlson and Westrum, 1971
Carlson, H.G.; Westrum, E.F., Jr.,
Methanol: heat capacity, enthalpies of transition and melting, and thermodynamic properties from 5-300K,
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Kelley, 1929
Kelley, K.K.,
The heat capacity of methyl alcohol from 16K to 298K and the corresponding entropy and free energy,
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Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M.,
Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds,
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Ahlberg, Blanchard, et al., 1937
Ahlberg, J.E.; Blanchard, E.R.; Lundberg, W.O.,
The heat capacities of benzene, methyl alcohol and glycerol at very low temperatures,
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Filatov and Afanas'ev, 1992
Filatov, V.A.; Afanas'ev, V.N.,
Differential heat-flux calorimeter, Izv. Vysshikh. Uchebn. Zaved.,
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Khasanshin and Zykova, 1989
Khasanshin, T.S.; Zykova, T.B.,
Specific heat of saturated monatomic alcohols,
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Andreoli-Ball, Patterson, et al., 1988
Andreoli-Ball, L.; Patterson, D.; Costas, M.; Caceres-Alonso, M.,
Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc.,
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Okano, Ogawa, et al., 1988
Okano, T.; Ogawa, H.; Murakami, S.,
Molar excess volumes, isentropic compressions, and isobaric heat capacities of methanol-isomeric butanol systems at 298.15 K,
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Lankford and Criss, 1987
Lankford, J.I.; Criss, C.M.,
Partial molar heat caqpacities of selected electrolytes and benzene in methanol and dimethyldulfoxide at 25, 40 and 80°C,
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Korolev, Kukharenko, et al., 1986
Korolev, V.P.; Kukharenko, V.A.; Krestov, G.A.,
Specific heat of binary mixtures of aliphatic alcohols with N,N-dimethylformamide and dimethylsulphoxide,
Zhur. Fiz. Khim., 1986, 60, 1854-1857. [all data]
Ogawa and Murakami, 1986
Ogawa, H.; Murakami, S.,
Excess isobaric heat capacities for water + alkanol mixtures at 298.15 K,
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Tanaka, Toyama, et al., 1986
Tanaka, R.; Toyama, S.; Murakami, S.,
Heat capacities of {xCnH2n+1OH+(1-x)C7H16} for n = 1 to 6 at 298.15 K,
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Costas and Patterson, 1985
Costas, M.; Patterson, D.,
Self-association of alcohols in inert solvents, J. Chem. Soc.,
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Zegers and Somsen, 1984
Zegers, H.C.; Somsen, G.,
Partial molar volumes and heat capacities in (dimethylformamide + an n-alkanol),
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Benson and D'Arcy, 1982
Benson, G.C.; D'Arcy, P.J.,
Excess isobaric heat capacities of water - n-alcohol mixtures,
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Villamanan, Casanova, et al., 1982
Villamanan, M.A.; Casanova, C.; Roux-Desgranges, G.; Grolier, J.-P.E.,
Thermochemical behavior of mixtures of n-alcohol + aliphatic ether: heat capacities and volumes at 298.15 K,
Thermochim. Acta, 1982, 52, 279-283. [all data]
Atalla, El-Sharkawy, et al., 1981
Atalla, S.R.; El-Sharkawy, A.A.; Gasser, F.A.,
Measurement of thermal properties of liquids with an AC heated-wire technique,
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Deshpande and Bhatagadde, 1971
Deshpande, D.D.; Bhatagadde, L.G.,
Heat capacities at constant volume, free volumes, and rotational freedom in some liquids,
Aust. J. Chem., 1971, 24, 1817-1822. [all data]
Paz Andrade, Paz, et al., 1970
Paz Andrade, M.I.; Paz, J.M.; Recacho, E.,
Contribucion a la microcalorimetria de los calores especificos de solidos y liquidos,
An. Quim., 1970, 66, 961-967. [all data]
Katayama, 1962
Katayama, T.,
Heats of mixing, liquid heat capacities and enthalpy, concentration charts for methanol-water and isopropanol-water systems,
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A semi-micro low-temperature calorimeter, and a comparison of some thermodynamic properties of methyl alcohol and methyl deuteroxide,
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Specific heats of acetone, methyl-, ethyl-, and n-propyl-alcohols at low temperatures,
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Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht,
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Notes
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- Symbols used in this document:
Cp,gas Constant pressure heat capacity of gas Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid S°liquid Entropy of liquid at standard conditions S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°gas Enthalpy of combustion of gas at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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