D-Mannose, 5TMS derivative

• Formula: C₂₁H₅₂O₆Si₅
• Molecular weight: 541.0615
• IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)23-17-19(25-30(7,8)9)21(27-32(13,14)15)20(26-31(10,11)12)18(16-22)24-29(4,5)6/h16,18-21H,17H2,1-15H3 Copy

  
• IUPAC Standard InChIKey: PPTMWEDTYQRQBC-UHFFFAOYSA-N Copy
• CAS Registry Number: 6736-99-8
• Chemical structure:
  This structure is also available as a 2d Mol file
• Species with the same structure:
  • D-Glucose, 5TMS derivative
• Stereoisomers:
  • D(-)-Fructose (Levulose), aldol, TMS
  • D(-)-Tagatose, aldol, TMS
  • L(-)-Sorbose, aldol, TMS
  • Galactose, pentakis-TMS
  • Glucose, pentakis-TMS
• Other names: Mannose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, D-; D-Mannose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-; D-Mannose, pentakis-TMS; Mannose, pentakis-TMS; B-D-Mannose, TMS; A-D-Mannose, TMS
• Information on this page:
  • Gas Chromatography
  • References
  • Notes
• Options:
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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

View large format table.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T., GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices, Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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