D-Glucose, 5TMS derivative
- Formula: C21H52O6Si5
- Molecular weight: 541.0615
- IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)23-17-19(25-30(7,8)9)21(27-32(13,14)15)20(26-31(10,11)12)18(16-22)24-29(4,5)6/h16,18-21H,17H2,1-15H3
- IUPAC Standard InChIKey: PPTMWEDTYQRQBC-UHFFFAOYSA-N
- CAS Registry Number: 6736-97-6
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Stereoisomers:
- Other names: D-Glucose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-; D-Glucose, pentakis-O-(trimethylsilyl)-; Pentakis-O-(trimethylsilyl)-D-glucose; D-Glucose, penta-TMS; Glucose, TMS; Glucose, TMS, # 2; B-Glucose TMS; B-D-Glucose, TMS; A-D-Glucose, TMS; L-Glucose, TMS; A-Glucose TMS; D-Glucose, TMS; Glucose, TMS # 1
- Information on this page:
- Other data available:
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5 | 1926. | Fu, Iga, et al., 2000 | 30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1930. | Yang and Cashman, 1992 | 30. m/0.32 mm/1.0 μm, He; Program: 3 min at 100 0C; 100 - 200 0C at 8 deg/min; 1 min at 200 0C; 200 - 280 0C at 5 deg/min; 30 min at 280 0C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-101 | 1937. | Binder and Haddon, 1984 | Helium; Column length: 42. m; Column diameter: 0.50 mm; Program: 60 0C (0.5 min) 30 0C/min -> 170 0C 3 0C/min -> 220 0C |
| Capillary | OV-101 | 1934. | Binder and Haddon, 1984 | Helium; Column length: 42. m; Column diameter: 0.50 mm; Program: 80 0C (0.5 min) 30 0C/min -> 170 0C 3 0C/min -> 220 0C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fu, Iga, et al., 2000
Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S.,
Simplified screening for organic acidemia using GC/MS and dried urine filter paper: a study on neonatal mass screening,
Early Hum. Dev., 2000, 58, 1, 41-55, https://doi.org/10.1016/S0378-3782(00)00053-0
. [all data]
Yang and Cashman, 1992
Yang, Z.C.; Cashman, J.R.,
Structure-retention index relationships for derivatized monosaccharides on non-polar gas chromatography columns,
J. Chromatogr., 1992, 596, 1, 79-84, https://doi.org/10.1016/0021-9673(92)80205-9
. [all data]
Binder and Haddon, 1984
Binder, R.B.; Haddon, W.F.,
Analysis of O-methylinositols by gas-liquid chromatography-mass spectrometry,
Carbohydrate Research, 1984, 129, 21-32, https://doi.org/10.1016/0008-6215(84)85295-7
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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