pentacontane
- Formula: C50H102
- Molecular weight: 703.3449
- CAS Registry Number: 6596-40-3
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 365.3 | K | N/A | Seyer, Patterson, et al., 1944 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 365.3 | K | N/A | Carothers, Hill, et al., 1930 | Uncertainty assigned by TRC = 1.5 K; TRC |
Tfus | 366.2 | K | N/A | Sinnatt and Barasch, 1920 | Uncertainty assigned by TRC = 3. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 60.35 ± 0.05 | kcal/mol | CGC | Chickos, Wang, et al., 2008 | Based on data from 323. to 523. K.; AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
35.6 | 618. | A,E | Stephenson and Malanowski, 1987 | Based on data from 603. to 852. K. See also Kudchadker and Zwolinski, 1966.; AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
44.2 | 366.9 | Hammami and Mehrotra, 1995 | AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Seyer, Patterson, et al., 1944
Seyer, W.F.; Patterson, R.F.; Keays, J.L.,
The Density and Transition Points of the n-Paraffin Hydrocarbons,
J. Am. Chem. Soc., 1944, 66, 179-82. [all data]
Carothers, Hill, et al., 1930
Carothers, W.H.; Hill, J.W.; Kirby, J.E.; Jacobson, R.A.,
Studies on Polymerization and Ring Formation. VII. Normal Paraffin Hydro- carbons of High Molecular Weight Prepared by the Action of Sodium on Decamethylene Bormide,
J. Am. Chem. Soc., 1930, 52, 5279. [all data]
Sinnatt and Barasch, 1920
Sinnatt, F.S.; Barasch, M.,
J. Soc. Chem. Ind. London, 1920, 39, 289A. [all data]
Chickos, Wang, et al., 2008
Chickos, James; Wang, Tracy; Sharma, Esseim,
Hypothetical Thermodynamic Properties: Vapor Pressures and Vaporization Enthalpies of the Even n -Alkanes from C 40 to C 76 at T = 298.15 K by Correlation-Gas Chromatography. Are the Vaporization Enthalpies a Linear Function of Carbon Number?,
J. Chem. Eng. Data, 2008, 53, 2, 481-491, https://doi.org/10.1021/je7005852
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kudchadker and Zwolinski, 1966
Kudchadker, A.P.; Zwolinski, B.J.,
Vapor Pressure and Boiling Points of Normal Alkanes, C 21 to C 100 .,
J. Chem. Eng. Data, 1966, 11, 2, 253-255, https://doi.org/10.1021/je60029a039
. [all data]
Hammami and Mehrotra, 1995
Hammami, Ahmed; Mehrotra, Anil K.,
Liquid-solid-solid thermal behaviour of n-C44H90 + n-C50H102 and n-C25H52 + n-C28H58 paraffinic binary mixtures,
Fluid Phase Equilibria, 1995, 111, 2, 253-272, https://doi.org/10.1016/0378-3812(95)02777-C
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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