lithium propionate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar143.17J/mol*KN/AFranzosini and Westrum, 1985 
solid,1 bar175.9J/mol*KN/AFranzosini and Westrum, 1984 

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
130.29298.15Franzosini and Westrum, 1985T = 5 to 350 K.
143.8298.15Franzosini and Westrum, 1984T = 10 to 600 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus606.5KN/AFerloni, Sanesi, et al., 1975Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple606.8KN/AFranzosini and Westrum, 1984, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
514.crystaline, IIcrystaline, IFranzosini and Westrum, 1984DH
606.8crystaline, IliquidFranzosini and Westrum, 1984DH

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
3.350533.crystaline, IIcrystaline, IFerloni, Sanesi, et al., 1975, 2DH
15.860606.5crystaline, IliquidFerloni, Sanesi, et al., 1975, 2Also metastable fusion at 584.6 K, H = 17824 J/mol.; DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
6.3533.crystaline, IIcrystaline, IFerloni, Sanesi, et al., 1975, 2DH
26.1606.5crystaline, IliquidFerloni, Sanesi, et al., 1975, 2Also; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Franzosini and Westrum, 1985
Franzosini, P.; Westrum, E.F., Recent investigations on the thermophysics of lithium soaps, 1985, Calorim. [all data]

Franzosini and Westrum, 1984
Franzosini, P.; Westrum, E.F., Jr., Thermophysics of metal alkanoates. III. Heat capacities and thermodynamic properties of lithium and potassium propanoates, J. Chem. Thermodynam., 1984, 16, 81-90. [all data]

Ferloni, Sanesi, et al., 1975
Ferloni, P.; Sanesi, M.; Franzosini, P., Phase transitions in the alkali C1-n.C4 alkanoates, Z. Naturforsch., A: Phys., Phys. Chem., Kosmophys., 1975, 30, 1447-57. [all data]

Franzosini and Westrum, 1984, 2
Franzosini, P.; Westrum, E.F., Thermophysics of metal alkanoates III. Heat capacities and thermodynamic properties of lithium and potassium propanoates, J. Chem. Thermodyn., 1984, 16, 81. [all data]

Ferloni, Sanesi, et al., 1975, 2
Ferloni, P.; Sanesi, M.; Franzosini, P.; C4 alkanoates, Phase transitions in the alkali C1-n., Z. Naturforsch. 30a, 1975, 1447-1454. [all data]


Notes

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