Benzene, 1-(1,5-dimethyl-4-hexenyl)-4-methyl-
- Formula: C15H22
- Molecular weight: 202.3352
- IUPAC Standard InChIKey: VMYXUZSZMNBRCN-UHFFFAOYSA-N
- CAS Registry Number: 644-30-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: α-Curcumene; 2-Heptene, 2-methyl-6-p-tolyl-; Ar-Curcumene; Curcumene; Curcumene AR; 2-Methyl-6-p-tolyl-2-heptene; 1-Methyl-4-(6-methylhept-5-en-2-yl)benzene; 1-(1,5-Dimethyl-4-hexenyl)-4-methylbenzene; ar. curcumene; Curcumene <AR>; <AR> curcumene; (-)-Ar-Curcumene; aromatic curcumene; Aryl-curcumene
- Permanent link for this species. Use this link for bookmarking this species for future reference.
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- Other data available:
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Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5MS | BP-1 | DB-5 | RTX-1 | SPB-1 |
Column length (m) | 30. | 50. | 30. | 60. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.22 | 0.25 | 0.22 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 60. | 50. |
Tend (C) | 250. | 220. | 240. | 230. | 250. |
Heat rate (K/min) | 2. | 2. | 3. | 2. | 5. |
Initial hold (min) | 8. | 3. | |||
Final hold (min) | 30. | 20. | 35. | 15. | |
I | 1485. | 1472. | 1483. | 1468. | 1464. |
Reference | Benkaci-Ali, Baaliouamer, et al., 2007 | Boti, Koukoua, et al., 2007 | Maccioni, Baldini, et al., 2007 | Paolini, Muselli, et al., 2007 | Radulovic, Lazarevic, et al., 2007 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5MS | DB-5 | DB-5 | HP-5MS | ZB-5 |
Column length (m) | 30. | 25. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 60. | 50. |
Tend (C) | 280. | 200. | 260. | 280. | 250. |
Heat rate (K/min) | 4. | 2. | 5. | 4. | 3. |
Initial hold (min) | 5. | 5. | |||
Final hold (min) | 60. | ||||
I | 1479. | 1482. | 1488. | 1479. | 1483. |
Reference | Radulovic, Lazarevic, et al., 2007 | Rout, Rao, et al., 2007 | Sabulal, Dan, et al., 2007 | Saroglou, Marin, et al., 2007 | Simoniatto, Bonani, et al., 2007 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | HP-5MS | RTX-1 | 5 % Phenyl methyl siloxane | BP-1 |
Column length (m) | 60. | 30. | 60. | 25. | 50. |
Carrier gas | N2 | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.22 | 0.25 | 0.22 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 80. | 60. | 60. | 60. |
Tend (C) | 250. | 300. | 230. | 280. | 220. |
Heat rate (K/min) | 5. | 4. | 2. | 3. | 2. |
Initial hold (min) | |||||
Final hold (min) | 10. | 45. | 20. | 20. | |
I | 1477. | 1485.8 | 1472. | 1479. | 1472. |
Reference | Sonboli, Azizian, et al., 2007 | Zeng, Zhao, et al., 2007 | Cavalli, Tomi, et al., 2006 | Djarri, Medjroubi, et al., 2006 | Duquesnoy, Dinh, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | BP-1 | HP-5 | DB-1 | RTX-1 | DB-5 |
Column length (m) | 50. | 30. | 30. | 60. | 30. |
Carrier gas | He | He | N2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.22 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 50. | 60. | 60. |
Tend (C) | 220. | 250. | 220. | 230. | 280. |
Heat rate (K/min) | 2. | 3. | 4. | 2. | 3. |
Initial hold (min) | |||||
Final hold (min) | 20. | 35. | |||
I | 1472. | 1484. | 1479. | 1470. | 1473. |
Reference | Gonny, Cavaleiro, et al., 2006 | Javidnia, Miri, et al., 2006 | Kuiate, Bessière, et al., 2006 | Paolini J., Desjobert J.M., et al., 2006 | Pavlovic, Tzakou, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | CP Sil 5 CB | CP Sil 5 CB | DB-1 | DB-1 |
Column length (m) | 30. | 25. | 25. | 30. | 25. |
Carrier gas | He | H2 | He | ||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.25 |
Phase thickness (μm) | 0.25 | 0.4 | 0.25 | 0.25 | |
Tstart (C) | 50. | 80. | 80. | 50. | 60. |
Tend (C) | 265. | 270. | 270. | 250. | 180. |
Heat rate (K/min) | 2.5 | 10. | 10. | 2. | 3. |
Initial hold (min) | 8. | 10. | |||
Final hold (min) | 10. | ||||
I | 1460. | 1473. | 1473. | 1477. | 1480. |
Reference | Ramezani, Behravan, et al., 2006 | Ziegenbein, Hanssen, et al., 2006 | Ziegenbein, Hanssen, et al., 2006, 2 | Dob, Dahmane, et al., 2005 | bin Jantan, Yalvema, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | HP-5MS | DB-5 | HP-5 | HP-5MS |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.26 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 50. | 60. |
Tend (C) | 260. | 250. | 210. | 290. | 280. |
Heat rate (K/min) | 3. | 4. | 3. | 4. | 4. |
Initial hold (min) | 2. | 5. | |||
Final hold (min) | 20. | ||||
I | 1480. | 1487. | 1470. | 1484. | 1481. |
Reference | Javidnia, Miri, et al., 2005 | Pino, Mesa, et al., 2005 | Sati and Mathela, 2005 | Flach A., Dondon R.C., et al., 2004 | Grujic-Jovanovic, Skaltsa, et al., 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | HP-5 | DB-5 | BP-1 | BP-1 |
Column length (m) | 25. | 30. | 25. | 50. | 50. |
Carrier gas | He | He | N2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.25 | 0.25 | 0.22 | 0.22 |
Phase thickness (μm) | 0.33 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 50. | 75. | 60. | 60. |
Tend (C) | 240. | 310. | 210. | 230. | 230. |
Heat rate (K/min) | 3. | 4. | 3. | 2. | 2. |
Initial hold (min) | 10. | ||||
Final hold (min) | 7. | 1. | 35. | 35. | |
I | 1483. | 1484. | 1481. | 1472. | 1472. |
Reference | Sartoratto, Machado, et al., 2004 | Singer, Flach, et al., 2004 | bin Ahmad and bin Jantan, 2003 | Bianchini, Tomi, et al., 2003 | Bianchini, Tomi, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | RTX-1 | Optima 5 | PE-5 | DB-5 | DB-5 |
Column length (m) | 60. | 25. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | N2 |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 60. | 60. | 40. | 75. | 75. |
Tend (C) | 230. | 280. | 280. | 230. | 230. |
Heat rate (K/min) | 2. | 3. | 3. | 3. | 3. |
Initial hold (min) | 10. | 10. | |||
Final hold (min) | 45. | 20. | 20. | ||
I | 1471. | 1469. | 1483. | 1479. | 1482. |
Reference | Cavalli, Tomi, et al., 2003 | Chosson, Vérité, et al., 2003 | Isidorov and Vinogorova, 2003 | Jantan, Ling, et al., 2003 | bin Jantan, Yassin, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | MS5 | HP-5 | HP-5 | DB-1 | SPB-5 |
Column length (m) | 25. | 30. | 30. | 25. | 30. |
Carrier gas | He | He | N2 | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 40. | 60. | 60. | 60. | 60. |
Tend (C) | 180. | 280. | 280. | 180. | 250. |
Heat rate (K/min) | 3. | 4. | 3. | 3. | 4. |
Initial hold (min) | 5. | 10. | 2. | ||
Final hold (min) | 10. | 20. | |||
I | 1477. | 1479. | 1483. | 1475. | 1483. |
Reference | Shao, Marriott, et al., 2003 | Skaltsa, Demetzos, et al., 2003 | Tzakou, Couladis, et al., 2003 | bin Jantan and bin Ahmad, 2002 | Pino, Marbot, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | HP-5 | BP-1 | HP-5 | DB-5 |
Column length (m) | 50. | 30. | 50. | 30. | 30. |
Carrier gas | He | He | He | He | H2 |
Substrate | |||||
Column diameter (mm) | 0.22 | 0.25 | 0.22 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.50 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 60. | 60. |
Tend (C) | 220. | 280. | 230. | 280. | 240. |
Heat rate (K/min) | 2. | 3. | 2. | 3. | 3. |
Initial hold (min) | 5. | ||||
Final hold (min) | 20. | 35. | |||
I | 1472. | 1481. | 1472. | 1483. | 1483. |
Reference | Pintore, Usai, et al., 2002 | Aligiannis, Kalpoutzakis, et al., 2001 | Bianchini, Tomi, et al., 2001 | Couladis, Tzakou, et al., 2001 | Nogueira, Bittrich, et al., 2001 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5MS | DB-5 | HP-5 | CP Sil 8 CB | BP-1 |
Column length (m) | 30. | 60. | 30. | 50. | 50. |
Carrier gas | He | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.22 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 60. | 40. | 50. | 60. | 60. |
Tend (C) | 280. | 290. | 280. | 220. | 220. |
Heat rate (K/min) | 4. | 4. | 4. | 4. | 2. |
Initial hold (min) | 5. | 2. | 5. | 5. | |
Final hold (min) | 5. | 30. | 20. | ||
I | 1479. | 1475. | 1478. | 1485. | 1471. |
Reference | Skaltsa, Mavrommati, et al., 2001 | Bartley and Jacobs, 2000 | Lazari, Skaltsa, et al., 2000 | Chevance and Farmer, 1999 | Mazzoni, Tomi, et al., 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Methyl Silicone | CP Sil 5 CB | OV-1 | Ultra-1 | BP-1 |
Column length (m) | 50. | 25. | 25. | 25. | 50. |
Carrier gas | N2 | He | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.22 |
Phase thickness (μm) | 0.17 | 0.3 | 0.52 | 0.25 | |
Tstart (C) | 80. | 60. | 50. | 35. | 60. |
Tend (C) | 200. | 260. | 200. | 320. | 230. |
Heat rate (K/min) | 2. | 5. | 3. | 15. | 2. |
Initial hold (min) | 1. | ||||
Final hold (min) | 20. | 10. | 35. | ||
I | 1499. | 1473. | 1458. | 1473. | 1473. |
Reference | Sumathykutty, Rao, et al., 1999 | Weyerstahl, Marschall, et al., 1999 | Bicchi, Rubiolo, et al., 1998 | Richmond and Pombo-Villar, 1998 | Mariotti, Costa, et al., 1997 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|
Active phase | Ultra-1 | DB-1 | OV-1 | OV-1 |
Column length (m) | 25. | 60. | 30. | 30. |
Carrier gas | He | He | ||
Substrate | ||||
Column diameter (mm) | 0.32 | 0.32 | 0.5 | 0.5 |
Phase thickness (μm) | 0.52 | 0.5 | 0.8 | 0.8 |
Tstart (C) | 35. | 40. | 40. | 40. |
Tend (C) | 320. | 290. | 220. | 220. |
Heat rate (K/min) | 15. | 4. | 2. | 2. |
Initial hold (min) | 2. | |||
Final hold (min) | 10. | 5. | ||
I | 1472.96 | 1475. | 1463. | 1468. |
Reference | Richmond and Pombo-Villar, 1997 | Bartley and Foley, 1994 | De Pooter, Omar, et al., 1985 | De Pooter, Omar, et al., 1985 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Benkaci-Ali, Baaliouamer, et al., 2007
Benkaci-Ali, F.; Baaliouamer, A.; Meklati, B.Y.; Chemat, F.,
Chemical composition of seed essential oils from Algerian Nigella sativa extracted by microwave and hydrodistillation,
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Boti, Koukoua, et al., 2007
Boti, J.B.; Koukoua, G.; N'Guessan, T.Y.; Casanova, J.,
Chemical variability of Conyza sumatrensis and Microglossa pyrifolia from Côte d'Ivoire,
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Maccioni, Baldini, et al., 2007
Maccioni, S.; Baldini, R.; Luigi Cioni, P.; Tebano, M.; Flamini, G.,
In vivo volatiles emission and essential oils from different organs and pollen of Cistus albidus from Caprione (Eastern Liguria, Italy),
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Paolini, Muselli, et al., 2007
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Thymol derivatives from essential oil of Doronicum corsicum L.,
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Chemotaxonomic significance of the volatiles in the genus Stachys (Lamiaceae): Essential oil composition of four Balkan Stachys species,
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Rout, Rao, et al., 2007
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Chemical composition and evaluation of antibacterial and antioxidant activities of the essential oil of Croton urucurana Baillon (Euphorbiaceae) stem bark,
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Djarri, Medjroubi, et al., 2006
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Chemical composition and antidermatophytic properties of the essential oils from leaves, flowers and fruits of Cupressus lusitanica Mill. from Cameroon,
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Ramezani, Behravan, et al., 2006
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Composition and antimicrobial activity of the volatile oil of Artemisia kopetdaghensis Krasch., M.Pop. Linecz ex Poljak from Iran,
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Ziegenbein, Hanssen, et al., 2006
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Secondary metabolites from Ganoderma lucidum and Spongiporus leucomallellus,
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Ziegenbein, Hanssen, et al., 2006, 2
Ziegenbein, F.C.; Hanssen, H.-P.; König, W.A.,
Chemical constituents of the essential oils of three wood-rotting fungi,
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Dob, Dahmane, et al., 2005
Dob, T.; Dahmane, D.; Berramdane, T.; Chelghoum, C.,
Chemical composition of the essential oil of Artemisia campestris L. from Algeria,
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bin Jantan, Yalvema, et al., 2005
bin Jantan, I.; Yalvema, M.F.; Ahmad, N.W.; Jamal, J.A.,
Insecticidal activities of the leaf oils of eight Cinnamomum species against Aedes aegypti and Aedes albopictus,
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Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
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