Bis(dimethylphosphino)methane

• Formula: C₅H₁₄P₂
• Molecular weight: 136.1122
• IUPAC Standard InChI: InChI=1S/C5H14P2/c1-6(2)5-7(3)4/h5H2,1-4H3 Copy

  
• IUPAC Standard InChIKey: MRNJHNUEBDGNEL-UHFFFAOYSA-N Copy
• CAS Registry Number: 64065-08-3
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C₅H₁₃P₂^- +  =

By formula: C₅H₁₃P₂^- + H⁺ = C₅H₁₄P₂

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C₅H₁₃P₂^- +  =

By formula: C₅H₁₃P₂^- + H⁺ = C₅H₁₄P₂

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Romer, Gatev, et al., 1998
Romer, B.; Gatev, G.G.; Zhong, M.; Brauman, J.I., Alpha-Stabilization by Silyl and Phosphino Substitution, J. Am. Chem. Soc., 1998, 120, 12, 2919, https://doi.org/10.1021/ja970279s . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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