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Propane, 2-ethoxy-2-methyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-317.8kJ/molN/ASharonov, Rozhnov, et al., 1995Value computed using «DELTA»fHliquid° value of -350.8±2.6 kj/mol from Sharonov, Rozhnov, et al., 1995 and «DELTA»vapH° value of 32.97 kj/mol from missing citation.; DRB
Deltafgas-314. ± 2.kJ/molEqkIborra, Izquierdo, et al., 1989GC; ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
149.33300.Dunphy M.P., 1991These values were calculated using estimated structural parameters and vibrational frequencies. According to estimation by difference method [ Dorofeeva O.V., 1997] the uncertainty of S(298.15 K) is evaluated to be 5-8 J/mol*K.; GT
193.03400.
232.27500.
264.66600.
291.26700.
313.57800.
332.53900.
348.941000.
363.071100.
375.411200.
386.181300.
395.621400.
403.881500.
411.121600.
417.491700.
423.081800.
428.021900.
432.442000.
436.362100.
439.842200.
442.952300.
445.742400.
448.292500.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharonov, Rozhnov, et al., 1995
Sharonov, K.G.; Rozhnov, A.M.; Korol'kov, A.V.; Karaseva, S.Y., Enthalpies of formation of 2-methyl-2-ethoxypropane and 2-ethyl-2-ethoxypropane from equilibrium measurements, J. Chem. Thermodyn., 1995, 27, 751-753. [all data]

Iborra, Izquierdo, et al., 1989
Iborra, M.; Izquierdo, J.F.; Tejero, J.; Cunill, F., Equilibrium constant for ethyl tert-butyl ether vapor-phase synthesis, J. Chem. Eng. Data, 1989, 34, 1-5. [all data]

Dunphy M.P., 1991
Dunphy M.P., Preliminary observations on the high temperature oxidation of ethyl tert-butyl ether, Int. J. Chem. Kinet., 1991, 23, 553-558. [all data]

Dorofeeva O.V., 1997
Dorofeeva O.V., Unpublished results. Thermocenter of Russian Academy of Science, Moscow, 1997. [all data]


Notes

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