Carbaril
- Formula: C12H11NO2
- Molecular weight: 201.2212
- IUPAC Standard InChI: InChI=1S/C12H11NO2/c1-13-12(14)15-11-8-4-6-9-5-2-3-7-10(9)11/h2-8H,1H3,(H,13,14)
- IUPAC Standard InChIKey: CVXBEEMKQHEXEN-UHFFFAOYSA-N
- CAS Registry Number: 63-25-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 1-Naphthalenol, methylcarbamate; Carbamic acid, methyl-, 1-naphthyl ester; α-Naphthalenyl methylcarbamate; α-Naphthyl methylcarbamate; α-Naphthyl N-methylcarbamate; Arilat; Arilate; Arylam; Atoxan; Bercema NMC50; Caprolin; Carbatox; Carbatox 75; Carbatox-60; Carbavur; Carpolin; Compound 7744; Denapon; Dicarbam; Dyna-carbyl; Experimental Insecticide 7744; ENT-23969; Gamonil; Germain's; Karbatox; Karbatox 75; Karbosep; Menaphtam; Monsur; Murvin; N-Methyl-α-Naphthylcarbamate; N-Methyl-α-naphthylurethan; N-Methyl-1-naphthyl carbamate; NAC; NMC 50; Panam; Pomex; Seffein; Sevimol; Sevin; Sevin 4; Sewin; Union Carbide 7744; Vioxan; 1-Naphthol N-methylcarbamate; 1-Naphthyl methylcarbamate; 1-Naphthyl N-methylcarbamate; α-Naftyl-N-methylkarbamat; Crag sevin; Dicarbament 23,969; Hexavin; Karbaryl; Karbaspray; Methylcarbamate, 1-naphthalenol; Methylcarbamic acid, 1-naphthyl ester; N-Methyl-1-naftyl-carbamaat; N-Methyl-1-naphthyl-carbamat; N-Methylcarbamate de 1-naphtyle; N-Metil-1-naftil-carbammato; OMS-29; Septene; Suleo; SOK; Tricarnam; UC 7744; 1-Naphthyl N-methylcarbamateacid O,O-diethyl ester; Mugan; Ravyon; Carbomate; Oltitox; Prosevor 85; Carbamic acid, N-methyl-1-naphthyl-; Carbamic acid, N-methyl,1-naphthyl ester; Carbamine; Carbarilo; Carbarilum; Carylderm; Clinicide; Derbac; Sevin SL; Thinsec; Tornado; Carbaryl; Laivin; 1-Naphthalenol, 1-(N-methylcarbamate); Adios; Vetox; Vetox 85
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1871. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
| Capillary | DB-5 | 1910. | Hall, Whitehead, et al., 1986 | He, 6. K/min; Column length: 15. m; Column diameter: 0.25 mm; Tstart: 100. C; Tend: 270. C |
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1903. | Tanabe, Mitobe, et al., 2000 | 30. m/0.32 mm/0.25 μm; Program: 50C(1min) => 20C/min => 150C => 10C/min => 280C(4min) |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | OV-1 | 1915. | Marozzi, Gambaro, et al., 1982 | Gas Chrom P, 2.5 K/min; Column length: 2. m; Tstart: 120. C; Tend: 200. C |
| Packed | SE-30 | 1865. | Marozzi, Gambaro, et al., 1982 | Gas Chrom P, 2.5 K/min; Column length: 2. m; Tstart: 120. C; Tend: 200. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | 5 % Phenyl methyl siloxane | 1912. | Department of Food Safety and Welfare, 2006 | 30. m/0.25 mm/0.25 μm, Helium; Program: 50 0C(1 min) 25 0C/min -> 125 0C 10 0C/min -> 300 0C (10 min) |
| Capillary | HP-5 | 1903. | Kawara, Asada, et al., 2005 | 30. m/0.25 mm/0.25 μm; Program: 50 0C (1 min) 20 0C/min -> 150 0C 10 0C/min -> 280 0C |
Normal alkane RI, polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Carbowax 20M | 2826. | Tameo and Kiyos, 1991 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hall, Whitehead, et al., 1986
Hall, G.L.; Whitehead, W.E.; Mourer, C.R.; Shibamoto, T.,
A new gas chromatographic retention index for pesticides and related compounds,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 5, 266-271, https://doi.org/10.1002/jhrc.1240090503
. [all data]
Tanabe, Mitobe, et al., 2000
Tanabe, A.; Mitobe, H.; Kawata, K.; Sakai, M.; Yasuhara, A.,
New monitoring system for ninety pesticides and related compounds in river water by solid-phase extraction with determination by gas chromatography/mass spectrometry,
J. AOAC Int., 2000, 83, 1, 61-77. [all data]
Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F.,
Use of the retention index in gas chromatographic studies of drugs,
J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185
. [all data]
Department of Food Safety and Welfare, 2006
Department of Food Safety, Ministry of Health; Welfare,
Analytical methods for residual compositional substances of agricultural chemicals, feed aadditives, and veterinary drugs in foods, 2006, retrieved from http://www.mhlw.go.jp/english/topics/foodsafety/positivelist060228/de/060526-1a.pdf. [all data]
Kawara, Asada, et al., 2005
Kawara, K.; Asada, T.; Oikawa, K.; Tanabe, A.,
Multiresidue determination of pesticides in sediments by ultrasonically assisted extraction and gas chromatography/mass spectrometry,
J. AOAC International, 2005, 88, 5, 1440-1451. [all data]
Tameo and Kiyos, 1991
Tameo, O.; Kiyos, I.,
Simultaneous determination of pesticides by capillary gas chromatography,
Cannot be traslated (in Japan), 1991, 14, 2, 109-122. [all data]
Notes
Go To: Top, Gas Chromatography, References
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