Butane, 2-chloro-3-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil366.15KN/AHass, McBee, et al., 1935Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
35.9300.AStephenson and Malanowski, 1987Based on data from 285. to 405. K. See also Dykyj, 1972.; AC

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Butane, 2-chloro-2-methyl- = Butane, 2-chloro-3-methyl-

By formula: C5H11Cl = C5H11Cl

Quantity Value Units Method Reference Comment
Δr9.12kJ/molEqkEsipenok, Kabo, et al., 1973liquid phase; solvent: liquid phase
Δr7.9 ± 0.2kJ/molEqkEsipenok, Kabo, et al., 1973liquid phase; solvent: cyclohexane

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin COMPAGNIE FRANCAISE DE RAFFINAGE, FRANCE.
NIST MS number 1365

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryApiezon L130.662.Arruda, Junkes, et al., 2008 
CapillarySqualane30.668.Tourres, 1968Nitrogen; Column length: 50. m; Column diameter: 0.25 mm
CapillarySqualane50.672.Tourres, 1968Nitrogen; Column length: 50. m; Column diameter: 0.25 mm

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone684.Zenkevich, 1999Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hass, McBee, et al., 1935
Hass, H.B.; McBee, E.T.; Weber, P., Ind. Eng. Chem., 1935, 27, 1190. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Esipenok, Kabo, et al., 1973
Esipenok, G.E.; Kabo, G.Ya.; Andreevskii, D.N., Equilibrium and thermodynamics of the isomerisation of methylchlorobutanes, Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 420. [all data]

Arruda, Junkes, et al., 2008
Arruda, A.C.S.; Junkes, B. da.S.; Souza, E.S.; Yunes, R.A.; Heizen, V.E.F., Semi-Emlirical Topological Index to Predict Properties of Halogenated Aliphatic Compounds, J. Chemometrics, 2008, 22, 3-4, 186-194, https://doi.org/10.1002/cem.1121 . [all data]

Tourres, 1968
Tourres, D.A., Separation of mono- and dichloro-methyl butanes and of monochloro-methyl butenes by preparative gas chromatography, Chromatographia, 1968, 1, 11-12, 437-442, https://doi.org/10.1007/BF02255759 . [all data]

Zenkevich, 1999
Zenkevich, I.G., Mutual Correlation between Gas-Chromatographic Retention Indices of Organic Compounds from Different Series, Zh. Anal. Khim., 1999, 54, 12, 1272-1279. [all data]


Notes

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