Tridecane
- Formula: C13H28
- Molecular weight: 184.3614
- IUPAC Standard InChIKey: IIYFAKIEWZDVMP-UHFFFAOYSA-N
- CAS Registry Number: 629-50-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: n-Tridecane; Tridecane, n-
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -377.7 ± 1.6 | kJ/mol | Ccb | Prosen and Rossini, 1945 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -8739.7 ± 1.4 | kJ/mol | Ccb | Prosen and Rossini, 1945 | Corresponding ΔfHºliquid = -377.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 522.87 | J/mol*K | N/A | Finke, Gross, et al., 1954 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
409.40 | 303.15 | Woycicka and Kalinowska, 1975 | DH |
406.89 | 298.15 | Finke, Gross, et al., 1954 | T = 12 to 310 K.; DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 507. ± 2. | K | AVG | N/A | Average of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 268. ± 1. | K | AVG | N/A | Average of 19 out of 20 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 267.79 ± 0.01 | K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 676. ± 1. | K | AVG | N/A | Average of 10 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 17. ± 1. | bar | N/A | Ambrose and Tsonopoulos, 1995 | |
Pc | 16.79 | bar | N/A | Rosenthal and Teja, 1989 | Uncertainty assigned by TRC = 0.20 bar; TRC |
Pc | 17.20 | bar | N/A | Teja, Lee, et al., 1989 | TRC |
Pc | 17.25 | bar | N/A | Pak and Kay, 1972 | Uncertainty assigned by TRC = 0.3447 bar; corrected for vapor pressure of Hg, and extrapolated to zero to correct for decomposition; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.823 | l/mol | N/A | Ambrose and Tsonopoulos, 1995 | |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 1.2 ± 0.1 | mol/l | N/A | Ambrose and Tsonopoulos, 1995 | |
ρc | 1.22 | mol/l | N/A | Anselme, Gude, et al., 1990 | Uncertainty assigned by TRC = 0.03 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 66.43 | kJ/mol | N/A | Majer and Svoboda, 1985 | |
ΔvapH° | 66.7 | kJ/mol | N/A | Ruzicka and Majer, 1994 | AC |
ΔvapH° | 66.5 ± 0.2 | kJ/mol | C | Sunner and Svensson, 1979 | AC |
ΔvapH° | 66.4 ± 0.3 | kJ/mol | C | Morawetz, 1972 | AC |
ΔvapH° | 66.2 | kJ/mol | N/A | Reid, 1972 | AC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 91.4 | kJ/mol | B | Morawetz, 1972, 2 | AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
65.3 | 309. | C | Viton, Chavret, et al., 1996 | AC |
64.9 | 314. | C | Viton, Chavret, et al., 1996 | AC |
64.2 | 324. | C | Viton, Chavret, et al., 1996 | AC |
63.3 | 334. | C | Viton, Chavret, et al., 1996 | AC |
62.4 | 344. | C | Viton, Chavret, et al., 1996 | AC |
62.3 | 349. | C | Viton, Chavret, et al., 1996 | AC |
54.5 | 432. | A | Stephenson and Malanowski, 1987 | Based on data from 417. to 511. K. See also Camin and Rossini, 1955.; AC |
65.6 | 308. | C | Sunner and Svensson, 1979 | AC |
64.6 | 318. | C | Sunner and Svensson, 1979 | AC |
61.7 | 348. | C | Sunner and Svensson, 1979 | AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | A (kJ/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
298. to 348. | 94.73 | 0.3468 | 675.8 | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
412.5 to 509.21 | 4.12829 | 1689.093 | -98.866 | Camin and Rossini, 1955 |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
28.9 | 267.7 | DSC | Mondieig, Rajabalee, et al., 2004 | AC |
28.49 | 267.8 | N/A | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
30.04 | 255. | Domalski and Hearing, 1996 | CAL |
106.27 | 267.8 |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
7.661 | 255.0 | crystaline, II | crystaline, I | Finke, Gross, et al., 1954 | DH |
28.501 | 267.79 | crystaline, I | liquid | Finke, Gross, et al., 1954 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
30.04 | 255.0 | crystaline, II | crystaline, I | Finke, Gross, et al., 1954 | DH |
106.43 | 267.79 | crystaline, I | liquid | Finke, Gross, et al., 1954 | DH |
Henry's Law data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
0.00043 | Q | N/A | missing citation give several references for the Henry's law constants but don't assign them to specific species. |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D.,
Heats of combustion and formation of the paraffin hydrocarbons at 25° C,
J. Res. NBS, 1945, 263-267. [all data]
Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M.,
Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane,
J. Am. Chem. Soc., 1954, 76, 333-341. [all data]
Woycicka and Kalinowska, 1975
Woycicka, M.K.; Kalinowska, B.,
Enthalpies of mixing and excess heat capacities of dilute solutions of n-decanol with n-heptane and n-tridecane, Bull. Acad. Pol. Sci.,
Ser. Sci. Chim., 1975, 23, 759-764. [all data]
Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C.,
Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes,
J. Chem. Eng. Data, 1995, 40, 531-546. [all data]
Rosenthal and Teja, 1989
Rosenthal, D.J.; Teja, A.S.,
The Critical Properties of n-Alkanes Using a Low-Residence Time Flow Apparatus,
AIChE J., 1989, 35, 1829. [all data]
Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J.,
Correlation of the Critical Properties of Alkanes and Alkanols
in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]
Pak and Kay, 1972
Pak, S.C.; Kay, W.B.,
Gas-Liquid Critical Temperatures of Mixtures. Benzene + n-Alkanes and Hexafluorobenzene + n-Alkanes,
Ind. Eng. Chem. Fundam., 1972, 11, 255. [all data]
Anselme, Gude, et al., 1990
Anselme, M.J.; Gude, M.; Teja, A.S.,
The Critical Temperatures and Densities of the n-Alkanes from Pentane to Octadecane,
Fluid Phase Equilib., 1990, 57, 317-26. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Ruzicka and Majer, 1994
Ruzicka, Kvetoslav; Majer, Vladimir,
Simultaneous Treatment of Vapor Pressures and Related Thermal Data Between the Triple and Normal Boiling Temperatures for n-Alkanes C5--C20,
J. Phys. Chem. Ref. Data, 1994, 23, 1, 1, https://doi.org/10.1063/1.555942
. [all data]
Sunner and Svensson, 1979
Sunner, Stig; Svensson, Christer,
Twin calorimeter for the determination of enthalpies of vaporization of small samples from 300 to 420 K,
J. Chem. Soc., Faraday Trans. 1, 1979, 75, 0, 2359, https://doi.org/10.1039/f19797502359
. [all data]
Morawetz, 1972
Morawetz, E.,
Enthalpies of vaporization of n-alkanes from C12 to C20,
J. Chem. Thermodyn., 1972, 4, 139-144. [all data]
Reid, 1972
Reid, Robert C.,
Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00,
AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637
. [all data]
Morawetz, 1972, 2
Morawetz, Ernst,
Correlation of sublimation enthalpies at 298.15 K with molecular structure for planar aromatic hydrocarbons,
The Journal of Chemical Thermodynamics, 1972, 4, 3, 461-467, https://doi.org/10.1016/0021-9614(72)90030-4
. [all data]
Viton, Chavret, et al., 1996
Viton, C.; Chavret, M.; Jose, J.,
Enthalpies of vaporization of normal alkanes from nonane to pentadecane at temperatures from 298 to 359 K,
ELDATA: Int. Electron. J. Phys. Chem. Data, 1996, 2, 3, 103. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Camin and Rossini, 1955
Camin, David L.; Rossini, Frederick D.,
Physical Properties of Fourteen API Research Hydrocarbons, C 9 to C 15,
J. Phys. Chem., 1955, 59, 11, 1173-1179, https://doi.org/10.1021/j150533a014
. [all data]
Mondieig, Rajabalee, et al., 2004
Mondieig, D.; Rajabalee, F.; Metivaud, V.; Oonk, H.A.J.; Cuevas-Diarte, M.A.,
n -Alkane Binary Molecular Alloys,
Chem. Mater., 2004, 16, 5, 786-798, https://doi.org/10.1021/cm031169p
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Henry's Law data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°liquid Entropy of liquid at standard conditions Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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