Tridecane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil507. ± 2.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus268. ± 1.KAVGN/AAverage of 19 out of 20 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple267.79 ± 0.01KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tc676. ± 1.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Pc17. ± 1.barN/AAmbrose and Tsonopoulos, 1995 
Pc16.79barN/ARosenthal and Teja, 1989Uncertainty assigned by TRC = 0.20 bar; TRC
Pc17.20barN/ATeja, Lee, et al., 1989TRC
Pc17.25barN/APak and Kay, 1972Uncertainty assigned by TRC = 0.3447 bar; corrected for vapor pressure of Hg, and extrapolated to zero to correct for decomposition; TRC
Quantity Value Units Method Reference Comment
Vc0.823l/molN/AAmbrose and Tsonopoulos, 1995 
Quantity Value Units Method Reference Comment
ρc1.2 ± 0.1mol/lN/AAmbrose and Tsonopoulos, 1995 
ρc1.22mol/lN/AAnselme, Gude, et al., 1990Uncertainty assigned by TRC = 0.03 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap66.43kJ/molN/AMajer and Svoboda, 1985 
Δvap66.7kJ/molN/ARuzicka and Majer, 1994AC
Δvap66.5 ± 0.2kJ/molCSunner and Svensson, 1979AC
Δvap66.4 ± 0.3kJ/molCMorawetz, 1972AC
Δvap66.2kJ/molN/AReid, 1972AC
Quantity Value Units Method Reference Comment
Δsub91.4kJ/molBMorawetz, 1972, 2AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
65.3309.CViton, Chavret, et al., 1996AC
64.9314.CViton, Chavret, et al., 1996AC
64.2324.CViton, Chavret, et al., 1996AC
63.3334.CViton, Chavret, et al., 1996AC
62.4344.CViton, Chavret, et al., 1996AC
62.3349.CViton, Chavret, et al., 1996AC
54.5432.AStephenson and Malanowski, 1987Based on data from 417. to 511. K. See also Camin and Rossini, 1955.; AC
65.6308.CSunner and Svensson, 1979AC
64.6318.CSunner and Svensson, 1979AC
61.7348.CSunner and Svensson, 1979AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) β Tc (K) Reference Comment
298. to 348.94.730.3468675.8Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference
412.5 to 509.214.128291689.093-98.866Camin and Rossini, 1955

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
28.9267.7DSCMondieig, Rajabalee, et al., 2004AC
28.49267.8N/ADomalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
30.04255.Domalski and Hearing, 1996CAL
106.27267.8

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
7.661255.0crystaline, IIcrystaline, IFinke, Gross, et al., 1954DH
28.501267.79crystaline, IliquidFinke, Gross, et al., 1954DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
30.04255.0crystaline, IIcrystaline, IFinke, Gross, et al., 1954DH
106.43267.79crystaline, IliquidFinke, Gross, et al., 1954DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + 1-Tridecene = Tridecane

By formula: H2 + C13H26 = C13H28

Quantity Value Units Method Reference Comment
Δr-125.8 ± 1.9kJ/molChydRogers and Skanupong, 1974liquid phase; solvent: Hexane

References

Go To: Top, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C., Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes, J. Chem. Eng. Data, 1995, 40, 531-546. [all data]

Rosenthal and Teja, 1989
Rosenthal, D.J.; Teja, A.S., The Critical Properties of n-Alkanes Using a Low-Residence Time Flow Apparatus, AIChE J., 1989, 35, 1829. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Pak and Kay, 1972
Pak, S.C.; Kay, W.B., Gas-Liquid Critical Temperatures of Mixtures. Benzene + n-Alkanes and Hexafluorobenzene + n-Alkanes, Ind. Eng. Chem. Fundam., 1972, 11, 255. [all data]

Anselme, Gude, et al., 1990
Anselme, M.J.; Gude, M.; Teja, A.S., The Critical Temperatures and Densities of the n-Alkanes from Pentane to Octadecane, Fluid Phase Equilib., 1990, 57, 317-26. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ruzicka and Majer, 1994
Ruzicka, Kvetoslav; Majer, Vladimir, Simultaneous Treatment of Vapor Pressures and Related Thermal Data Between the Triple and Normal Boiling Temperatures for n-Alkanes C5--C20, J. Phys. Chem. Ref. Data, 1994, 23, 1, 1, https://doi.org/10.1063/1.555942 . [all data]

Sunner and Svensson, 1979
Sunner, Stig; Svensson, Christer, Twin calorimeter for the determination of enthalpies of vaporization of small samples from 300 to 420 K, J. Chem. Soc., Faraday Trans. 1, 1979, 75, 0, 2359, https://doi.org/10.1039/f19797502359 . [all data]

Morawetz, 1972
Morawetz, E., Enthalpies of vaporization of n-alkanes from C12 to C20, J. Chem. Thermodyn., 1972, 4, 139-144. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Morawetz, 1972, 2
Morawetz, Ernst, Correlation of sublimation enthalpies at 298.15 K with molecular structure for planar aromatic hydrocarbons, The Journal of Chemical Thermodynamics, 1972, 4, 3, 461-467, https://doi.org/10.1016/0021-9614(72)90030-4 . [all data]

Viton, Chavret, et al., 1996
Viton, C.; Chavret, M.; Jose, J., Enthalpies of vaporization of normal alkanes from nonane to pentadecane at temperatures from 298 to 359 K, ELDATA: Int. Electron. J. Phys. Chem. Data, 1996, 2, 3, 103. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Camin and Rossini, 1955
Camin, David L.; Rossini, Frederick D., Physical Properties of Fourteen API Research Hydrocarbons, C 9 to C 15, J. Phys. Chem., 1955, 59, 11, 1173-1179, https://doi.org/10.1021/j150533a014 . [all data]

Mondieig, Rajabalee, et al., 2004
Mondieig, D.; Rajabalee, F.; Metivaud, V.; Oonk, H.A.J.; Cuevas-Diarte, M.A., n -Alkane Binary Molecular Alloys, Chem. Mater., 2004, 16, 5, 786-798, https://doi.org/10.1021/cm031169p . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M., Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane, J. Am. Chem. Soc., 1954, 76, 333-341. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]


Notes

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