Ethylene glycol, dinitrate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-55.6kcal/molCcbRinkenbach, 1926 
Quantity Value Units Method Reference Comment
Δcliquid-268.48kcal/molCcbRinkenbach, 1926 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap16.8kcal/molAStephenson and Malanowski, 1987Based on data from 283. to 535. K.
Quantity Value Units Method Reference Comment
Δsub24.81kcal/molTE,MENunez, Barral, et al., 1988 

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.2358.AStephenson and Malanowski, 1987Based on data from 343. to 465. K.
16.3255.N/AStephenson and Malanowski, 1987Based on data from 240. to 298. K. See also Pella, 1977.
14.9 ± 0.1278. to 390.N/ABelyaev, 1941 
16.4 ± 0.1293. to 323.N/ABrander, 1938 

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
25.12361.TE,MEDe Wit, Van Miltenburg, et al., 1983Based on data from 345. to 372. K.
25.19369.MEBradley and Cleasby, 1953Based on data from 360. to 378. K. See also Jones, 1960 and Stephenson and Malanowski, 1987.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rinkenbach, 1926
Rinkenbach, W.H., The properties of glycol dinitrate, Ind. Eng. Chem., 1926, 18, 1195-1197. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Nunez, Barral, et al., 1988
Nunez, L.; Barral, L.; Pilcher, G., Enthalpies of combustion of oxamic acid, oxamide, and dithiooxamide, J. Chem. Thermodyn., 1988, 20, 1211-1216. [all data]

Pella, 1977
Pella, Peter A., Measurement of the vapor pressures of tnt, 2,4-dnt, 2,6-dnt, and egdn, The Journal of Chemical Thermodynamics, 1977, 9, 4, 301-305, https://doi.org/10.1016/0021-9614(77)90049-0 . [all data]

Belyaev, 1941
Belyaev, A.F., Acta Physicochim. URSS, 1941, 14, 523. [all data]

Brander, 1938
Brander, J.D., Nitroglycerin and Ethylene Glycol Dinitrate Vapor Pressures of Binary Solutions, Ind. Eng. Chem., 1938, 30, 6, 681-684, https://doi.org/10.1021/ie50342a015 . [all data]

De Wit, Van Miltenburg, et al., 1983
De Wit, H.G.M.; Van Miltenburg, J.C.; De Kruif, C.G., Thermodynamic properties of molecular organic crystals containing nitrogen, oxygen, and sulphur 1. Vapour pressures and enthalpies of sublimation, The Journal of Chemical Thermodynamics, 1983, 15, 7, 651-663, https://doi.org/10.1016/0021-9614(83)90079-4 . [all data]

Bradley and Cleasby, 1953
Bradley, R.S.; Cleasby, T.G., 346. The vapour pressure and lattice energy of hydrogen-bonded crystals. Part I. Oxamide, oxamic acid, and rubeanic acid, J. Chem. Soc., 1953, 1681, https://doi.org/10.1039/jr9530001681 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]


Notes

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