Methylene diacetate

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-780.66 ± 0.93kJ/molCcbVerevkin, Peng, et al., 1996 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-837.04 ± 0.91kJ/molCcbVerevkin, Peng, et al., 1996 
Quantity Value Units Method Reference Comment
Δcliquid-2273.83 ± 0.91kJ/molCcbVerevkin, Peng, et al., 1996Corresponding Δfliquid = -837.04 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap56.38 ± 0.25kJ/molVVerevkin, Peng, et al., 1996ALS
Δvap56.4kJ/molN/AVerevkin, Peng, et al., 1996DRB

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
50.6349.AStephenson and Malanowski, 1987Based on data from 334. to 443. K.; AC

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Verevkin, Peng, et al., 1996
Verevkin, S.P.; Peng, W.-H.; Beckhaus, H.D.; Ruchardt, C., Thermochemical study of aliphatic and phenyl-substituted germinal diacetates, Struct. Chem., 1996, 7, 397-404. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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