Peroxide, diethyl

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-193.kJ/molCcbBaker, Littlefair, et al., 1965 
Δfgas-200.kJ/molCmRebbert and Laidler, 1952 
Δfgas-280.kJ/molCcbStathis and Egerton, 1940 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-223.kJ/molCcbBaker, Littlefair, et al., 1965 
Δfliquid-233.kJ/molCmRebbert and Laidler, 1952 
Quantity Value Units Method Reference Comment
Δcliquid-2780. ± 1.kJ/molCcbBaker, Littlefair, et al., 1965Corresponding Δfliquid = -223. kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-2771.kJ/molCmRebbert and Laidler, 1952Corresponding Δfliquid = -233. kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-2697.9 ± 0.84kJ/molCcbStathis and Egerton, 1940Corresponding Δfliquid = -305.3 kJ/mol (simple calculation by NIST; no Washburn corrections)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baker, Littlefair, et al., 1965
Baker, G.; Littlefair, J.H.; Shaw, R.; Thynne, J.C.J., 1286. The heats of formation of dimethyl, diethyl, and di-t-butyl peroxide, J. Chem. Soc., 1965, 6970-6972. [all data]

Rebbert and Laidler, 1952
Rebbert, R.E.; Laidler, K.J., Kinetics of the decomposition of diethyl peroxide, J. Chem. Phys., 1952, 20, 574-577. [all data]

Stathis and Egerton, 1940
Stathis, E.C.; Egerton, A.C., Note on heats of formation of ethyl and propyl peroxides, Trans. Faraday Soc., 1940, 36, 606. [all data]


Notes

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