Peroxide, diethyl

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap31.kJ/molEBaker, Littlefair, et al., 1965ALS
Δvap30.0kJ/molN/ABaker, Littlefair, et al., 1965DRB
Δvap33.0kJ/molN/ARebbert and Laidler, 1952DRB
Δvap30.5kJ/molVBlat, Gerber, et al., 1939ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
29.0268.AStephenson and Malanowski, 1987Based on data from 253. to 333. K. See also Egerton, Emte, et al., 1951 and Dykyj, 1971.; AC
29.00253.VEgerton, Emte, et al., 1951ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baker, Littlefair, et al., 1965
Baker, G.; Littlefair, J.H.; Shaw, R.; Thynne, J.C.J., 1286. The heats of formation of dimethyl, diethyl, and di-t-butyl peroxide, J. Chem. Soc., 1965, 6970-6972. [all data]

Rebbert and Laidler, 1952
Rebbert, R.E.; Laidler, K.J., Kinetics of the decomposition of diethyl peroxide, J. Chem. Phys., 1952, 20, 574-577. [all data]

Blat, Gerber, et al., 1939
Blat, E.J.; Gerber, M.J.; Neumann, M.B., The influence of organic peroxides on the cool flame of butane, Acta Physicochim. U.R.S.S., 1939, 10, 273-296. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Egerton, Emte, et al., 1951
Egerton, A.C.; Emte, W.; Minkoff, G.J., Some properties of organic peroxides, Faraday Discuss. Chem. Soc., 1951, 10, 278. [all data]

Dykyj, 1971
Dykyj, J., Petrochemia, 1971, 11, 2, 27. [all data]


Notes

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