Peroxide, diethyl

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-193.kJ/molCcbBaker, Littlefair, et al., 1965 
Δfgas-200.kJ/molCmRebbert and Laidler, 1952 
Δfgas-280.kJ/molCcbStathis and Egerton, 1940 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-223.kJ/molCcbBaker, Littlefair, et al., 1965 
Δfliquid-233.kJ/molCmRebbert and Laidler, 1952 
Quantity Value Units Method Reference Comment
Δcliquid-2780. ± 1.kJ/molCcbBaker, Littlefair, et al., 1965Corresponding Δfliquid = -223. kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-2771.kJ/molCmRebbert and Laidler, 1952Corresponding Δfliquid = -233. kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-2697.9 ± 0.84kJ/molCcbStathis and Egerton, 1940Corresponding Δfliquid = -305.3 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap31.kJ/molEBaker, Littlefair, et al., 1965ALS
Δvap30.0kJ/molN/ABaker, Littlefair, et al., 1965DRB
Δvap33.0kJ/molN/ARebbert and Laidler, 1952DRB
Δvap30.5kJ/molVBlat, Gerber, et al., 1939ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
29.0268.AStephenson and Malanowski, 1987Based on data from 253. to 333. K. See also Egerton, Emte, et al., 1951 and Dykyj, 1971.; AC
29.00253.VEgerton, Emte, et al., 1951ALS

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin N.C.PAUL M.O.D., AVIATION SUPPLY, E.R.D.E., WALTHAM ABBEY U
NIST MS number 38597

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baker, Littlefair, et al., 1965
Baker, G.; Littlefair, J.H.; Shaw, R.; Thynne, J.C.J., 1286. The heats of formation of dimethyl, diethyl, and di-t-butyl peroxide, J. Chem. Soc., 1965, 6970-6972. [all data]

Rebbert and Laidler, 1952
Rebbert, R.E.; Laidler, K.J., Kinetics of the decomposition of diethyl peroxide, J. Chem. Phys., 1952, 20, 574-577. [all data]

Stathis and Egerton, 1940
Stathis, E.C.; Egerton, A.C., Note on heats of formation of ethyl and propyl peroxides, Trans. Faraday Soc., 1940, 36, 606. [all data]

Blat, Gerber, et al., 1939
Blat, E.J.; Gerber, M.J.; Neumann, M.B., The influence of organic peroxides on the cool flame of butane, Acta Physicochim. U.R.S.S., 1939, 10, 273-296. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Egerton, Emte, et al., 1951
Egerton, A.C.; Emte, W.; Minkoff, G.J., Some properties of organic peroxides, Faraday Discuss. Chem. Soc., 1951, 10, 278. [all data]

Dykyj, 1971
Dykyj, J., Petrochemia, 1971, 11, 2, 27. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References