Mercury, diethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid100.1 ± 4.2kJ/molReviewMartinho SimõesMS
Δfliquid31.2 ± 5.2kJ/molReviewMartinho SimõesMS
Δfliquid32.2 ± 5.3kJ/molReviewMartinho SimõesMS
Δfliquid30.2 ± 1.5kJ/molReviewMartinho SimõesSelected data. Average of the values from Carson, Carson, et al., 1952 and Hartley, Pritchard, et al., 1951.; MS
Δfliquid27.2 ± 0.8kJ/molCC-SBCarson, Carson, et al., 1952Value corrected based on a set of ancillary data by J.A. Martinho Simões; Please also see Cox and Pilcher, 1970. The enthalpy of combustion is not reported in Carson, Carson, et al., 1952.; MS
Quantity Value Units Method Reference Comment
Δcliquid-3103.3 ± 4.2kJ/molCC-SBLautsch, Erzberger, et al., 1958Please also see Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
Δfsolid72.0kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcsolid-3075.2kJ/molCC-SBBerthelot, 1899Please also see Berthelot, 1900.; MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
182.3298.15Burchalova, Kamelova, et al., 1978T = 5 to 300 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Carson, Carson, et al., 1952
Carson, A.S.; Carson, E.M.; Wilmshurst, B., Nature, 1952, 170, 320. [all data]

Hartley, Pritchard, et al., 1951
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. IV. Mercury diethyl and mercury diphenyl, Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Berthelot, 1899
Berthelot, M., Compt. Rend., 1899, 129, 918. [all data]

Berthelot, 1900
Berthelot, M., Ann. Chim. Phys., 1900, 20, 158. [all data]

Burchalova, Kamelova, et al., 1978
Burchalova, G.V.; Kamelova, G.P.; Nistratov, V.P.; Sheiman, M.S.; Rabinovich, I.B., Low-temperature heat capacity of diethylmercury, Termodin. Org. Soedin., 1978, (7), 21-22. [all data]


Notes

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