Butane, 1,1-dichloro-3-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil402.75KN/APomerantz, Fookson, et al., 1954Uncertainty assigned by TRC = 0.5 K
Tboil400.65KN/ASchmerling, 1949Uncertainty assigned by TRC = 3. K
Tboil401.KN/ASchmerling, 1946Uncertainty assigned by TRC = 3. K
Tboil403.85KN/AKohlraush and Koppl, 1935Uncertainty assigned by TRC = 2. K

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Butane, 1,1-dichloro-3-methyl- = 1-Butene, 1-chloro-3-methyl-, (Z)- + Hydrogen chloride

By formula: C5H10Cl2 = C5H9Cl + HCl

Quantity Value Units Method Reference Comment
Δr15.14 ± 0.10kcal/molEqkMeged, Levanova, et al., 1978gas phase; Gas phase

Butane, 1,1-dichloro-3-methyl- = trans-1-Chloro-3-methyl-1-butene

By formula: C5H10Cl2 = C5H9Cl

Quantity Value Units Method Reference Comment
Δr15.80 ± 0.10kcal/molEqkMeged, Levanova, et al., 1978gas phase; Gas phase

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin A. A. POLYAKOVA MOSCOW LOMONOSOV STATE UNIV., MOSCOW, USSR
NIST MS number 3772

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References

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pomerantz, Fookson, et al., 1954
Pomerantz, P.; Fookson, A.; Mears, T.W.; Rothberg, S.; Howard, F.L., Synthesis and Physical Properties of Several Acetylenic Hydrocarbons, J. Res. Natl. Bur. Stand. (U. S.), 1954, 52, 51. [all data]

Schmerling, 1949
Schmerling, L., , 1949. [all data]

Schmerling, 1946
Schmerling, L., Condensation of Saturated Halides with Unsaturated Compounds II. The Condensation of ALkyl Halides with Monohaloolefins, J. Am. Chem. Soc., 1946, 68, 1650-4. [all data]

Kohlraush and Koppl, 1935
Kohlraush, K.W.F.; Koppl, F., The Raman effect. XXXVIII. Raman spectra of organic substances. S. Isomeric paraffin derivatives., Monatsh. Chem., 1935, 65, 185. [all data]

Meged, Levanova, et al., 1978
Meged, V.M.; Levanova, S.V.; Shevtsova, L.A.; Rozhnev, A.M., Dehydrochlorination of 1,1-dichloro-3-methylbutane and geometric isomerization of chloromethylbutenes, Russ. J. Phys. Chem. (Engl. Transl.), 1978, 52, 285. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References