1-Tetradecanol, TMS derivative
- Formula: C17H38OSi
- Molecular weight: 286.5685
- IUPAC Standard InChI: InChI=1S/C17H38OSi/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(2,3)4/h5-17H2,1-4H3
- IUPAC Standard InChIKey: NPGKUGMPPAYNBX-UHFFFAOYSA-N
- CAS Registry Number: 6221-89-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1-Trimethylsilyloxytetradecane; 1-Tetradecanol, trimethylsilyl ether; 1-Tetradecanol, O-TMS; Silane, trimethyl(tetradecyloxy)-; Tetradecyl trimethylsilyl ether
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | NIST Mass Spectrometry Data Center |
| NIST MS number | 333298 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | SE-30 | 140. | 1754. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | Carbowax 20M | 140. | 1750. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1770. | Peng, 1992 | 15. m/0.53 mm/1. μm, 40. C @ 4. min, 8. K/min; Tend: 250. C |
| Capillary | OV-1 | 1768. | Harvey, 1989 | 50. m/0.30 mm/0.52 μm, He, 2. K/min; Tstart: 130. C; Tend: 280. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1754.7 | Zheng and White, 2008 | 30. m/0.25 mm/0.25 μm, He; Program: not specified |
| Capillary | VF-5MS | 1754.4 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
| Capillary | VF-5MS | 1757.4 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
Van Den Dool and Kratz RI, polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Carbowax 20M | 1759. | Peng, 1992 | 8. K/min, 200. C @ 60. min; Column length: 3.05 m; Tstart: 40. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-30 | 1775. | Poole and Zlatkis, 1979 | Program: not specified |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zarazir, Chovin, et al., 1970
Zarazir, D.; Chovin, P.; Guiochon, G.,
Identification of hydroxylic compounds and their derivatives by gas chromatography,
Chromatographia, 1970, 3, 4, 180-195, https://doi.org/10.1007/BF02269018
. [all data]
Peng, 1992
Peng, C.T.,
A method for tentative identificatoin of unknown gas chromatographic peaks by retention index,
J. Radioanal. Nucl. Chem., 1992, 160, 2, 449-460, https://doi.org/10.1007/BF02037120
. [all data]
Harvey, 1989
Harvey, D.J.,
Identification of long-chain fatty acids and alcohols from human cerumen by the use of picolinyl and nicotinate esters,
Biomed. Environ. Mass Spectrom., 1989, 18, 9, 719-723, https://doi.org/10.1002/bms.1200180912
. [all data]
Zheng and White, 2008
Zheng, Y.; White, E.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2008. [all data]
Tret'yakov, 2007
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]
Poole and Zlatkis, 1979
Poole, C.F.; Zlatkis, A.,
Trialkylsilyl Ether Derivatives (Other Than TMS) for Gas Chromatography and Mass Spectrometry,
J. Chromatogr. Sci., 1979, 17, 3, 115-123, https://doi.org/10.1093/chromsci/17.3.115
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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