1-Dodecanol, TMS derivative
- Formula: C15H34OSi
- Molecular weight: 258.5154
- IUPAC Standard InChI: InChI=1S/C15H34OSi/c1-5-6-7-8-9-10-11-12-13-14-15-16-17(2,3)4/h5-15H2,1-4H3
- IUPAC Standard InChIKey: ASWTVWBPXCLXKJ-UHFFFAOYSA-N
- CAS Registry Number: 6221-88-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Silane, (dodecyloxy)trimethyl-; (Dodecyloxy)(trimethyl)silane; 1-Dodecanol, trimethylsilyl ether; 1-Dodecanol, O-TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | SE-30 | 140. | 1564. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | Carbowax 20M | 140. | 1568. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1575. | Peng, 1992 | 15. m/0.53 mm/1. μm, 40. C @ 4. min, 8. K/min; Tend: 250. C |
| Capillary | OV-1 | 1571. | Harvey, 1989 | 50. m/0.30 mm/0.52 μm, He, 2. K/min; Tstart: 130. C; Tend: 280. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1559.6 | Zheng and White, 2008 | 30. m/0.25 mm/0.25 μm, He; Program: not specified |
| Capillary | VF-5MS | 1558.1 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
| Capillary | Methyl Silicone | 1575. | Peng, Yang, et al., 1991 | Program: not specified |
Van Den Dool and Kratz RI, polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Carbowax 20M | 1573. | Peng, 1992 | 8. K/min, 200. C @ 60. min; Column length: 3.05 m; Tstart: 40. C |
| Packed | Carbowax 20M | 1573. | Peng, Yang, et al., 1991 | Supelcoport, 40. C @ 4. min, 8. K/min; Column length: 3.05 m; Tend: 200. C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zarazir, Chovin, et al., 1970
Zarazir, D.; Chovin, P.; Guiochon, G.,
Identification of hydroxylic compounds and their derivatives by gas chromatography,
Chromatographia, 1970, 3, 4, 180-195, https://doi.org/10.1007/BF02269018
. [all data]
Peng, 1992
Peng, C.T.,
A method for tentative identificatoin of unknown gas chromatographic peaks by retention index,
J. Radioanal. Nucl. Chem., 1992, 160, 2, 449-460, https://doi.org/10.1007/BF02037120
. [all data]
Harvey, 1989
Harvey, D.J.,
Identification of long-chain fatty acids and alcohols from human cerumen by the use of picolinyl and nicotinate esters,
Biomed. Environ. Mass Spectrom., 1989, 18, 9, 719-723, https://doi.org/10.1002/bms.1200180912
. [all data]
Zheng and White, 2008
Zheng, Y.; White, E.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2008. [all data]
Tret'yakov, 2007
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]
Peng, Yang, et al., 1991
Peng, C.T.; Yang, Z.C.; Maltby, D.,
Prediction of retention indexes. III. Silylated derivatives of polar compounds,
J. Chromatogr., 1991, 586, 1, 113-129, https://doi.org/10.1016/0021-9673(91)80029-G
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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