2,2-Dimethoxy-3,3-dimethyl-butane


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2,2-Dimethoxy-3,3-dimethyl-butane + Water = 2Methyl Alcohol + 2-Butanone, 3,3-dimethyl-

By formula: C8H18O2 + H2O = 2CH4O + C6H12O

Quantity Value Units Method Reference Comment
Δr0.819 ± 0.013kcal/molCmWiberg and Squires, 1979liquid phase; Heat of hydrolysis

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Squires, 1979
Wiberg, K.B.; Squires, R.R., Thermodynamics of hydrolysis aliphatic ketals. An entropy component of steric effects, J. Am. Chem. Soc., 1979, 101, 5512-5515. [all data]


Notes

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