Silane, triethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil380. to 381.KN/APCR Inc., 1990BS
Tboil382.KN/AParnes, Khotimskaya, et al., 1969Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δvap8.9 ± 0.1kcal/molCVoronkov, Baryshok, et al., 1988AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
8.01303. to 373.EB,IBragin and Karapet'yants, 1975AC

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen anion + Silane, triethyl- = (Hydrogen anion • Silane, triethyl-)

By formula: H- + C6H16Si = (H- • C6H16Si)

Quantity Value Units Method Reference Comment
Δr20.0 ± 4.0kcal/molIMRBHajdasz, Ho, et al., 1994gas phase; affinity order: Et3SiH≤Et2SiH2≤nPnSiH3≤SiH4. nPnSiH3 is 0.4±0.2 kcal/mol > Et3SiH in ΔG. Et3SiH dHf(77PR) is wrong.
Δr10.2 ± 5.5kcal/molIMRBHajdasz and Squires, 1986gas phase

IR Spectrum

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Data compiled by: Coblentz Society, Inc.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 189996

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Parnes, Khotimskaya, et al., 1969
Parnes, Z.N.; Khotimskaya, G.A.; Kudryavtsev, R.V.; Lukina, M.Y.; Kursanov, D.N., The Behavior of Cyclopropane Hydrocarbons in Ionic Hydrogenation Reactions, Dokl. Akad. Nauk SSSR, Ser. Khim., 1969, 184, 615-8. [all data]

Voronkov, Baryshok, et al., 1988
Voronkov, M.G.; Baryshok, V.P.; Klyuchnikov, V.A.; Danilova, T.F.; Pepekin, V.I.; Korchagina, A.N.; Khudobin, Yu.I., Thermochemistry of organosilicon compounds, Journal of Organometallic Chemistry, 1988, 345, 1-2, 27-38, https://doi.org/10.1016/0022-328X(88)80231-6 . [all data]

Bragin and Karapet'yants, 1975
Bragin, G.P.; Karapet'yants, M.Kh., Tr. Khim. Khim. Tekhnol., 1975, 4, 78. [all data]

Hajdasz, Ho, et al., 1994
Hajdasz, D.J.; Ho, Y.; Squires, R.R., Gas-Phase Chemistry of Pentacoordinate Silicon Hydrides, J. Am. Chem. Soc., 1994, 116, 23, 10751, https://doi.org/10.1021/ja00102a045 . [all data]

Hajdasz and Squires, 1986
Hajdasz, D.J.; Squires, R.R., Hypervalent silicon hydrides: SiH5-, J. Am. Chem. Soc., 1986, 108, 3139. [all data]


Notes

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