Stibine, triethyl-
- Formula: C6H15Sb
- Molecular weight: 208.943
- IUPAC Standard InChIKey: KKOFCVMVBJXDFP-UHFFFAOYSA-N
- CAS Registry Number: 617-85-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Triethylantimony; Triethylstibine; (C2H5)3Sb
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 11.6 ± 2.7 | kcal/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 1.2 ± 2.6 | kcal/mol | Review | Martinho Simões | MS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -1162.6 ± 2.5 | kcal/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
57.899 | 298.15 | Maslova, Novoselova, et al., 1973 | T = 60 to 300 K.; DH |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 153.9 | K | N/A | Maslova, Novoselova, et al., 1973, 2 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10.9 | kcal/mol | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K.; AC |
ΔvapH° | 10.4 ± 1.0 | kcal/mol | CC-SB | Bamford, Levi, et al., 1946 | MS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
11.4 | 260. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K.; AC |
10.6 | 320. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K.; AC |
9.89 | 360. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K. See also Bamford, Levi, et al., 1946, 2.; AC |
9.15 | 400. | N/A | Fulem, Ruzicka, et al., 2006 | Based on data from 238. to 309. K. See also Bamford, Levi, et al., 1946, 2.; AC |
9.54 ± 0.31 | 306. | N/A | Baev, 2001 | Based on data from 193. to 333. K.; AC |
9.99 | 273. to 393. | BG | Bamford, Levi, et al., 1946, 2 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.259 | 153.9 | Maslova, Novoselova, et al., 1973 | DH |
2.26 | 153.9 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
14.68 | 153.9 | Maslova, Novoselova, et al., 1973 | DH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Maslova, Novoselova, et al., 1973
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B.,
Specific heat and phase changes of triethylindium, triethyl antimony, and trimethyl gallium,
Trudy. Khim. Khim. Tekhnol., 1973, (2), 51-52. [all data]
Maslova, Novoselova, et al., 1973, 2
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B.,
Specific Heat and Phase Changes of Triethylindium, Triethylantimony, and Trimethylgallium,
Tr. Khim. Khim. Tekhnol., 1973, 1973, 51. [all data]
Fulem, Ruzicka, et al., 2006
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Simecek, T.; Hulicius, E.; Pangrác, J.,
Vapour pressure measurement of metal organic precursors used for MOVPE,
The Journal of Chemical Thermodynamics, 2006, 38, 3, 312-322, https://doi.org/10.1016/j.jct.2005.05.018
. [all data]
Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M.,
J. Chem. Soc., 1946, 468.. [all data]
Bamford, Levi, et al., 1946, 2
Bamford, C.H.; Levi, D.L.; Newitt, D.M.,
91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V,
J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468
. [all data]
Baev, 2001
Baev, A.K.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Ttriple Triple point temperature ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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