Naphthalene, 2-phenyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil618.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus375.2KN/ABinns and Squire, 1962Uncertainty assigned by TRC = 1.5 K; TRC
Tfus375.KN/AKlemm, Reed, et al., 1957Uncertainty assigned by TRC = 3. K; TRC
Tfus374.4KN/AKochetkov, Nifant'ev, et al., 1957Uncertainty assigned by TRC = 2. K; TRC
Tfus374.9KN/AKutz, Nickels, et al., 1948Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δsub107.6 ± 0.6kJ/molMERocha, Lima, et al., 2008Based on data from 333. to 353. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
460.70.007Weast and Grasselli, 1989BS

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
106.6 ± 0.4343.MERocha, Lima, et al., 2008Based on data from 333. to 353. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
17.9373.5DSCRocha, Lima, et al., 2008AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin ANDERSON PHYSICAL LABORATORY
Source reference COBLENTZ NO. 2591
Date Not specified, most likely prior to 1970
State SOLID (1.0% IN KBr PELLET)
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Path length 0.0355 CM THICK
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS)

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 113420

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Binns and Squire, 1962
Binns, E.H.; Squire, K.H., Trans. Faraday Soc., 1962, 58, 762. [all data]

Klemm, Reed, et al., 1957
Klemm, L.H.; Reed, D.; Lind, C.D., J. Org. Chem., 1957, 22, 739. [all data]

Kochetkov, Nifant'ev, et al., 1957
Kochetkov, N.K.; Nifant'ev, E.E.; Nesmeyanov, A.N., Cyclic Acetals of β-Oxoaldehydes and Their Use in Synthesis of Alkylnaphthalenes, Izv. Akad. Nauk S.S.S.R., 1957, 1957, 949-55. [all data]

Kutz, Nickels, et al., 1948
Kutz, W.M.; Nickels, J.E.; McGovern, J.J.; Corson, B.B., Catalytic Alkylation of Indan and 1,2,3,4-Tetrahydronaphthalene by Olefins Alcohols and Diethyl Ether, J. Am. Chem. Soc., 1948, 70, 4026. [all data]

Rocha, Lima, et al., 2008
Rocha, Marisa A.A.; Lima, Carlos F.R.A.C.; Santos, Luís M.N.B.F., Phase transition thermodynamics of phenyl and biphenyl naphthalenes, The Journal of Chemical Thermodynamics, 2008, 40, 9, 1458-1463, https://doi.org/10.1016/j.jct.2008.04.010 . [all data]


Notes

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References