Dieldrin

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Phase change data

Go To: Top, Henry's Law data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus448.KN/APlato, 1972Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
Tfus453.KN/APlato, 1972Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
Tfus452.0KN/APlato and Glasgow, 1969Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
82.5398.GCHinckley, Bidleman, et al., 1990Based on data from 343. to 453. K.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
93.8328.GSGrayson and Fosbraey, 2006Based on data from 308. to 348. K.; AC
98.7303.GSSpencer and Cliath, 1969Based on data from 293. to 313. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
3.04452.9DSCKsia«807»azczak and Nagata, 1995AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Henry's Law data

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
5700. QN/AValue at T = 288. K.
92. LN/A 

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Henry's Law data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 114985

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

Go To: Top, Phase change data, Henry's Law data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-1190.2127.Erdmann, Rochholz, et al., 1992 
CapillaryOV-1220.2169.Erdmann, Rochholz, et al., 1992 
PackedOV-1200.2137.Dubsky, Hána, et al., 1979Column length: 2. m
PackedOV-1210.2159.Dubsky, Hána, et al., 1979Column length: 2. m

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
PackedSE-302170.Osselton and Snelling, 1986N2, Chromosorb W HP; Column length: 2. m; Program: not specified

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-12107.de Paoli, Taccheo-Barbina, et al., 199125. m/0.32 mm/0.10 μm, 160. C @ 1. min, 1. K/min; Tend: 240. C
CapillaryOV-12111.de Paoli, Taccheo-Barbina, et al., 199125. m/0.32 mm/0.10 μm, 160. C @ 1. min, 1.3 K/min; Tend: 240. C
CapillaryOV-12114.de Paoli, Taccheo-Barbina, et al., 199125. m/0.32 mm/0.10 μm, 160. C @ 1. min, 1.3 K/min; Tend: 240. C
CapillaryOV-12108.de Paoli, Taccheo-Barbina, et al., 199125. m/0.32 mm/0.10 μm, 160. C @ 1. min, 1.5 K/min; Tend: 240. C
CapillaryOV-12111.de Paoli, Taccheo-Barbina, et al., 199125. m/0.32 mm/0.10 μm, 160. C @ 1. min, 2. K/min; Tend: 240. C
CapillaryOV-12114.de Paoli, Taccheo-Barbina, et al., 199125. m/0.32 mm/0.10 μm, 160. C @ 1. min, 2. K/min; Tend: 240. C
CapillarySP-21002110.45Podmaniczky, Szepesy, et al., 1986H2, 2. K/min; Tstart: 170. C
CapillarySP-21002112.80Podmaniczky, Szepesy, et al., 1986H2, 4. K/min; Tstart: 170. C
CapillarySP-21002118.88Podmaniczky, Szepesy, et al., 1986H2, 6. K/min; Tstart: 170. C
CapillarySP-21002125.66Podmaniczky, Szepesy, et al., 1986H2, 2. K/min; Tstart: 170. C
CapillarySP-21002120.14Podmaniczky, Szepesy, et al., 1986H2, 4. K/min; Tstart: 170. C
CapillarySP-21002132.97Podmaniczky, Szepesy, et al., 1986H2, 6. K/min; Tstart: 170. C
CapillaryCP Sil 5 CB2132.35Podmaniczky, Szepesy, et al., 1986H2, 4. K/min; Tstart: 170. C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
PackedOV-12150.Marozzi, Gambaro, et al., 1982Gas Chrom P, 2.5 K/min; Column length: 2. m; Tstart: 120. C; Tend: 200. C
PackedSE-302175.Marozzi, Gambaro, et al., 1982Gas Chrom P, 2.5 K/min; Column length: 2. m; Tstart: 120. C; Tend: 200. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.2109.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.2139.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.2140.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-12139.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
OtherMethyl Silicone2110.Ardrey and Moffat, 1981Program: not specified
OtherMethyl Silicone2170.Ardrey and Moffat, 1981Program: not specified
OtherMethyl Silicone2175.Ardrey and Moffat, 1981Program: not specified

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySuperox 0.6; Carbowax 20M3103.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.3103.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

References

Go To: Top, Phase change data, Henry's Law data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Plato, 1972
Plato, C., DSC as a general method for determining purity and heat of fusion of high-purity organic chemicals, Anal. Chem., 1972, 44, 1531. [all data]

Plato and Glasgow, 1969
Plato, C.; Glasgow, A.R., Jr., Differential scanning calorimetry as a general method for determining the purity and heat of fusion of high-purity organic chemicals. Application to 95 compounds, Anal. Chem., 1969, 41, 2, 330, https://doi.org/10.1021/ac60271a041 . [all data]

Hinckley, Bidleman, et al., 1990
Hinckley, Daniel A.; Bidleman, Terry F.; Foreman, William T.; Tuschall, Jack R., Determination of vapor pressures for nonpolar and semipolar organic compounds from gas chromatograhic retention data, J. Chem. Eng. Data, 1990, 35, 3, 232-237, https://doi.org/10.1021/je00061a003 . [all data]

Grayson and Fosbraey, 2006
Grayson, B. Terence; Fosbraey, Lynda A., Determination of the vapour pressure of pesticides, Pestic. Sci., 2006, 13, 3, 269-278, https://doi.org/10.1002/ps.2780130308 . [all data]

Spencer and Cliath, 1969
Spencer, William F.; Cliath, M.M., Vapor density of dieldrin, Environ. Sci. Technol., 1969, 3, 7, 670-674, https://doi.org/10.1021/es60030a006 . [all data]

Ksia«807»azczak and Nagata, 1995
Ksia«807»azczak, A.; Nagata, I., Crystal-plastic and plastic-liquid phase transitions, and purity determination, Thermochimica Acta, 1995, 254, 31-39, https://doi.org/10.1016/0040-6031(94)02032-J . [all data]

Erdmann, Rochholz, et al., 1992
Erdmann, F.; Rochholz, G.; Schütz, H., Retention-indices on OV-1 of approximately 170 commonly used pesticides, Mikrochim. Acta, 1992, 106, 3-6, 219-226, https://doi.org/10.1007/BF01242093 . [all data]

Dubsky, Hána, et al., 1979
Dubsky, H.; Hána, K.; Komárková, M.; Rittich, B., Stanoveni residui chlórovanych pesticidu plynovou chromatografii, Vet. Med. (Prague), 1979, 24, 3, 493-498. [all data]

Osselton and Snelling, 1986
Osselton, M.D.; Snelling, R.D., Chromatographic Identification of Pesticides, J. Chromatogr., 1986, 368, 265-271, https://doi.org/10.1016/S0021-9673(00)91068-9 . [all data]

de Paoli, Taccheo-Barbina, et al., 1991
de Paoli, M.; Taccheo-Barbina, M.; Bontempelli, G., Gas chromatographic system for the identification of halogenated pesticides by retention indices using n-alkanes as standards, J. Chromatogr., 1991, 547, 355-365, https://doi.org/10.1016/S0021-9673(01)88659-3 . [all data]

Podmaniczky, Szepesy, et al., 1986
Podmaniczky, L.; Szepesy, L.; Lakszner, K.; Schomburg, G., Determination of Retention Indices in LPTGC, Chromatographia, 1986, 21, 7, 387-391, https://doi.org/10.1007/BF02346137 . [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Waggott and Davies, 1984
Waggott, A.; Davies, I.W., Identification of organic pollutants using linear temperature programmed retention indices (LTPRIs) - Part II, 1984, retrieved from http://dwi.defra.gov.uk/research/completed-research/reports/dwi0383.pdf. [all data]

Ardrey and Moffat, 1981
Ardrey, R.E.; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Chromatogr., 1981, 220, 3, 195-252, https://doi.org/10.1016/S0021-9673(00)81925-1 . [all data]


Notes

Go To: Top, Phase change data, Henry's Law data, Mass spectrum (electron ionization), Gas Chromatography, References