trans-Perfluorodecalin
- Formula: C10F18
- Molecular weight: 462.0783
- IUPAC Standard InChIKey: UWEYRJFJVCLAGH-IJWZVTFUSA-N
- CAS Registry Number: 60433-12-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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Gas phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -871.06 ± 0.93 | kcal/mol | Ccr | Zhogina, Papina, et al., 1987 |
Phase change data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 294.61 | K | N/A | Zhogin, Kosarukina, et al., 1981 | Uncertainty assigned by TRC = 0.01 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 10.9 ± 0.02 | kcal/mol | C | Varushchenko, Druzhinina, et al., 1996 | AC |
ΔvapH° | 10.9 ± 0.02 | kcal/mol | C | Zhogina, Papina, et al., 1987 | ALS |
ΔvapH° | 11.0 ± 0.1 | kcal/mol | EB | Varushchenko, Bulgakova, et al., 1981 | AC |
ΔvapH° | 10.9 ± 0.02 | kcal/mol | C | Varushchenko, Bulgakova, et al., 1981 | AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
10.3 | 330. | Dykyj, Svoboda, et al., 1999 | Based on data from 315. to 417. K.; AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
4.2930 | 294.61 | Zhogin, Kosarukina, et al., 1981, 2 | DH |
4.293 | 294.6 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
14.60 | 294.61 | Zhogin, Kosarukina, et al., 1981, 2 | DH |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhogina, Papina, et al., 1987
Zhogina, E.V.; Papina, T.S.; Kolesov, V.P.; Mel'nichenko, B.A.; Zapol'skaya, M.A.; Prokudin, I.P.,
Standard enthalpies of formation of cis- and trans-perfluorodecalins,
Russ. J. Phys. Chem. (Engl. Transl.), 1987, 61, 1523-1525. [all data]
Zhogin, Kosarukina, et al., 1981
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P.,
The heat capacities in the range 6-310 K, phase transformation, and thermodynamic functions of perfluorodecalins,
Zh. Fiz. Khim., 1981, 55, 1955. [all data]
Varushchenko, Druzhinina, et al., 1996
Varushchenko, Raisa M.; Druzhinina, Anna I.; Pashchenko, Larisa L.,
Thermodynamics of vaporization of some cyclic perfluorocarbons,
Fluid Phase Equilibria, 1996, 126, 1, 93-104, https://doi.org/10.1016/S0378-3812(96)03111-1
. [all data]
Varushchenko, Bulgakova, et al., 1981
Varushchenko, R.M.; Bulgakova, L.L.; Minzabekyants, P.S.; Makarov, K.N.,
Russ. J. Phys. Chem., 1981, 55, 1480. [all data]
Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R.,
Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]
Zhogin, Kosarukina, et al., 1981, 2
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P.,
The heat capacity in the range 6-310 K, phase transformations, and thermodynamic functions of perfluorodecalins,
Zhur. Fiz. Khim., 1981, 55, 1955-1960. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Ttriple Triple point temperature ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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