Perfluorodecaline, cis-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-866.2 ± 1.1kcal/molCcrZhogina, Papina, et al., 1987 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-877.2 ± 1.1kcal/molCcrZhogina, Papina, et al., 1987ALS
Quantity Value Units Method Reference Comment
Δcliquid-833.2 ± 1.1kcal/molCcrZhogina, Papina, et al., 1987ALS
Quantity Value Units Method Reference Comment
liquid123.0cal/mol*KN/AZhogin, Kosarukina, et al., 1981DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
107.5298.15Zhogin, Kosarukina, et al., 1981T = 6 to 310 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple266.70KN/AZhogin, Kosarukina, et al., 1981, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Δvap11.0 ± 0.02kcal/molCVarushchenko, Druzhinina, et al., 1996AC
Δvap11.04 ± 0.029kcal/molCZhogina, Papina, et al., 1987ALS
Δvap11.2 ± 0.1kcal/molEBVarushchenko, Bulgakova, et al., 1981AC
Δvap11.0 ± 0.02kcal/molCVarushchenko, Bulgakova, et al., 1981AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
10.5328.Dykyj, Svoboda, et al., 1999Based on data from 313. to 415. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.46266.7Domalski and Hearing, 1996AC

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.014232.5crystaline, IIcrystaline, IZhogin, Kosarukina, et al., 1981DH
2.4630266.70crystaline, IliquidZhogin, Kosarukina, et al., 1981DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
4.359232.5crystaline, IIcrystaline, IZhogin, Kosarukina, et al., 1981DH
9.230266.70crystaline, IliquidZhogin, Kosarukina, et al., 1981DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin A.Pleshkova, Nesmeyanov Inst.Org.Elem.Cpds, Moscow
NIST MS number 283804

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhogina, Papina, et al., 1987
Zhogina, E.V.; Papina, T.S.; Kolesov, V.P.; Mel'nichenko, B.A.; Zapol'skaya, M.A.; Prokudin, I.P., Standard enthalpies of formation of cis- and trans-perfluorodecalins, Russ. J. Phys. Chem. (Engl. Transl.), 1987, 61, 1523-1525. [all data]

Zhogin, Kosarukina, et al., 1981
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P., The heat capacity in the range 6-310 K, phase transformations, and thermodynamic functions of perfluorodecalins, Zhur. Fiz. Khim., 1981, 55, 1955-1960. [all data]

Zhogin, Kosarukina, et al., 1981, 2
Zhogin, D.Yu.; Kosarukina, E.A.; Kolesov, V.P., The heat capacities in the range 6-310 K, phase transformation, and thermodynamic functions of perfluorodecalins, Zh. Fiz. Khim., 1981, 55, 1955. [all data]

Varushchenko, Druzhinina, et al., 1996
Varushchenko, Raisa M.; Druzhinina, Anna I.; Pashchenko, Larisa L., Thermodynamics of vaporization of some cyclic perfluorocarbons, Fluid Phase Equilibria, 1996, 126, 1, 93-104, https://doi.org/10.1016/S0378-3812(96)03111-1 . [all data]

Varushchenko, Bulgakova, et al., 1981
Varushchenko, R.M.; Bulgakova, L.L.; Minzabekyants, P.S.; Makarov, K.N., Russ. J. Phys. Chem., 1981, 55, 1480. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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