Bismuthine, triphenyl-

• Formula: C₁₈H₁₅Bi
• Molecular weight: 440.2921
• IUPAC Standard InChI: InChI=1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H; Copy

  
• IUPAC Standard InChIKey: ZHXAZZQXWJJBHA-UHFFFAOYSA-N Copy
• CAS Registry Number: 603-33-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Bismuth triphenyl; Triphenylbismuth; Triphenylbismuthine; (C6H5)3Bi; Aerotex; Trifenylbismutin
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Steele, 1979
Steele, W.V., J. Chem. Thermodyn., 1979, 11, 187. [all data]

Birr, 1961
Birr, K.-H., Z. Anorg. Allg. Chem., 1961, 311, 92. [all data]

Birr, 1960
Birr, K.-H., Z. Anorg. Allg. Chem., 1960, 306, 21. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Steele, 1979, 2
Steele, W.V., The standard enthalpies of formation of the triphenyl compounds of the group V elements. 2. Triphenylbismuth and the Ph-Bi mean bond-dissociation energy, J. Chem. Thermodynam., 1979, 11, 187-192. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931, 2
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  Tfus	Fusion (melting) point
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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