Ethylmalonic acid

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-203.1 ± 0.26kcal/molCcbAl-Takhin, Pilcher, et al., 1983 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-228.3 ± 0.24kcal/molCcbAl-Takhin, Pilcher, et al., 1983 
Quantity Value Units Method Reference Comment
Δcsolid-519.18kcal/molCcbVerkade and Coops, 1933At 288 °K; Corresponding Δfsolid = -224.34 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tfus384.KN/AVogel, 1948Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δsub26.96 ± 0.53kcal/molMERibeiro da Silva, Monte, et al., 2000AC
Δsub25.2 ± 0.1kcal/molCAl-Takhin, Pilcher, et al., 1983ALS
Δsub25.22kcal/molN/AAl-Takhin, Pilcher, et al., 1983DRB

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Al-Takhin, Pilcher, et al., 1983
Al-Takhin, G.; Pilcher, G.; Bickerton, J., Standard enthalpies of formation of diamine(dicarboxylato)platinum(II) complexes and of bis(pentane-2,4-dionato)platinum(II): the mean Pt-O bond dissociation enthalpies, J. Chem. Soc. Dalton Trans., 1983, 2657-2659. [all data]

Verkade and Coops, 1933
Verkade, P.E.; Coops, J., Jr., Alternation phenomena VI (calorimetric researches XX): alternations in the properties of n.monoalkylmalonic acids. Some remarks on malkins views concerning the alternation phenonema, Recl. Trav. Chim. Pays-Bas, 1933, 52, 747-767. [all data]

Vogel, 1948
Vogel, A.I., J. Chem. Soc., 1948, 1948, 624-44. [all data]

Ribeiro da Silva, Monte, et al., 2000
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Ribeiro, José R., Standard Enthalpies, Entropies, and Gibbs Functions of Sublimation of Four Alkyl-Substituted Malonic Acids, J. Chem. Eng. Data, 2000, 45, 5, 756-759, https://doi.org/10.1021/je000090n . [all data]


Notes

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