Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-
- Formula: C10H16
- Molecular weight: 136.2340
- IUPAC Standard InChI: InChI=1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1
- IUPAC Standard InChIKey: XMGQYMWWDOXHJM-JTQLQIEISA-N
- CAS Registry Number: 5989-54-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: p-Mentha-1,8-diene, (S)-(-)-; (-)-Limonene; L-Limonene; Limonene; (S)-p-mentha-1,8-diene
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 449.2 | K | N/A | Aldrich Chemical Company Inc., 1990 | BS |
| Tboil | 449.4 | K | N/A | Von Braun and Lemke, 1923 | Uncertainty assigned by TRC = 2. K; TRC |
| Tboil | 449.4 | K | N/A | Lebedev and Skawronskaja, 1911 | Uncertainty assigned by TRC = 3. K; TRC |
| Tboil | 450. | K | N/A | Wallach and Conrady, 1889 | Uncertainty assigned by TRC = 6. K; TRC |
| Tboil | 449. | K | N/A | Wallach, 1888 | Uncertainty assigned by TRC = 4. K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔvapH° | 49.0 ± 0.1 | kJ/mol | C | Atik, Saito, et al., 1987 | AC |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 47.0 | 340. | N/A | Nadais and Bernardo-Gil, 1993 | Based on data from 325. to 450. K.; AC |
| 45.5 | 318. | A | Stephenson and Malanowski, 1987 | Based on data from 303. to 363. K. See also Bukala, Majewski, et al., 1954.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Von Braun and Lemke, 1923
Von Braun, J.; Lemke, G.,
Ber. Dtsch. Chem. Ges., 1923, 56, 1562. [all data]
Lebedev and Skawronskaja, 1911
Lebedev, S.; Skawronskaja, F.,
Zh. Russ. Fiz.-Khim. O-va., Chast Khim., 1911, 43, 1136. [all data]
Wallach and Conrady, 1889
Wallach, O.; Conrady, B.,
Justus Liebigs Ann. Chem., 1889, 252, 141. [all data]
Wallach, 1888
Wallach, O.,
Justus Liebigs Ann. Chem., 1888, 246, 221. [all data]
Atik, Saito, et al., 1987
Atik, Zadjia; Saito, Yoshihiro; Kusano, Kazuhito,
Thermodynamic properties of liquid enantiomers I. Enthalpies of vaporization of fenchones, α-methylbenzylamines, and limonenes at 298.15 K,
The Journal of Chemical Thermodynamics, 1987, 19, 1, 99-102, https://doi.org/10.1016/0021-9614(87)90167-4
. [all data]
Nadais and Bernardo-Gil, 1993
Nadais, M. Helena; Bernardo-Gil, M.G.,
Vapour - liquid equilibria of α-pinene + limonene at reduced pressures,
Fluid Phase Equilibria, 1993, 91, 2, 321-330, https://doi.org/10.1016/0378-3812(93)85107-W
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Bukala, Majewski, et al., 1954
Bukala, M.; Majewski, J.; Rodzinski, W.,
Przem. Chem., 1954, 10, 6. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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