Carbamic acid, methyl ester

• Formula: C₂H₅NO₂
• Molecular weight: 75.0666
• IUPAC Standard InChI: InChI=1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4) Copy

  
• IUPAC Standard InChIKey: GTCAXTIRRLKXRU-UHFFFAOYSA-N Copy
• CAS Registry Number: 598-55-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Methyl carbamate; Methylurethane; Urethylane; Methylurethan; NCI-C55594; Methylester kyseliny karbaminove; Methylkarbamat
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Mass spectrum (electron ionization)
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Reduced pressure boiling point

Enthalpy of vaporization

Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Bernard, Boukari, et al., 1976
Bernard, M.A.; Boukari, Y.; Busnot, F., Thermodynamic Study of Methyl and Ethyl Carbamates and Their Eutectics, Thermochim. Acta, 1976, 6, 267. [all data]

Bernard, Boukari, et al., 1976, 2
Bernard, M.A.; Boukari, Y.; Busnot, F., Thermodynamic study of methyl and ethyl carbamates and their eutectic, Thermochim. Acta, 1976, 16, 267-275. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Davies and Jones, 1959
Davies, Mansel; Jones, A. Hamilton, Lattice energies of some n-methyl amides and of some carbamates, Trans. Faraday Soc., 1959, 55, 1329, https://doi.org/10.1039/tf9595501329 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Notes

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• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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