Stannane, tetraethyl-
- Formula: C8H20Sn
- Molecular weight: 234.954
- IUPAC Standard InChIKey: RWWNQEOPUOCKGR-UHFFFAOYSA-N
- CAS Registry Number: 597-64-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetraethyltin; Tetraethylstannane; (C2H5)4Sn; Tin, tetraethyl-; TET
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Phase change data
Go To: Top, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 473.1 | K | N/A | Dibrivnyi, Dolbneva, et al., 1986 | Uncertainty assigned by TRC = 0.5 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 142.14 | K | N/A | Staveley, Warren, et al., 1954 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 141.9 | K | N/A | Maslova, Rabinovich, et al., 1972 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 50.6 ± 0.2 | kJ/mol | CC-SB | Abraham and Irving, 1980 | Another value for the enthalpy of vaporization has been reported: 51.0 ± 2.1 kJ/mol Davies, Pope, et al., 1963.; MS |
ΔvapH° | 50.6 ± 0.2 | kJ/mol | C | Abraham and Irving, 1980, 2 | AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
46.6 ± 0.6 | 374. | N/A | Baev, 2001 | Based on data from 293. to 455. K.; AC |
42.4 | 313. to 393. | GC | Hawker, 1992 | AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
9.146 | 142.14 | Staveley, Warren, et al., 1954, 2 | DH |
9.15 | 142.1 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
64.35 | 142.14 | Staveley, Warren, et al., 1954, 2 | DH |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
-1.090 | 121.4 | crystaline, II | crystaline, I | Maslova, Rabinovich, et al., 1972, 2 | Metastable transition.; DH |
8.929 | 141.9 | crystaline, I | liquid | Maslova, Rabinovich, et al., 1972, 2 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
62.9 | 141.9 | crystaline, I | liquid | Maslova, Rabinovich, et al., 1972, 2 | DH |
IR Spectrum
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Gas Phase Spectrum
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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | NIST Standard Reference Data Program Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Sadtler Research Labs Under US-EPA Contract |
State | gas |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 162550 |
References
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dibrivnyi, Dolbneva, et al., 1986
Dibrivnyi, V.N.; Dolbneva, T.N.; Dikii, M.A.,
Saturated vapor pressure and vaporization enthalpies of aromatic peroxides
in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 11th, Novosibirsk, Nr 2, p 115, 1986. [all data]
Staveley, Warren, et al., 1954
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J.,
Some Thermodynamic Properties of Compounds of the Formula MX4 II. Tetraalkyl Compounds,
J. Chem. Soc., 1954, 1954, 1992. [all data]
Maslova, Rabinovich, et al., 1972
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A.,
Specific heat and phase transition of some alkyl compounds of silicon, germanium, and tin,
Tr. Khim. Khim. Tekhnol., 1972, 1972, 44. [all data]
Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J.,
J. Chem. Thermodyn., 1980, 12, 539. [all data]
Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin,
Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233
. [all data]
Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J.,
Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds,
The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4
. [all data]
Baev, 2001
Baev, A.K.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]
Hawker, 1992
Hawker, Darryl,
Equilibrium vapour pressures of tetraorganostannanes,
Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W
. [all data]
Staveley, Warren, et al., 1954, 2
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J.,
Some thermodynamic properties of compounds of the formula MX4. Part II. Tetra-alkyl compounds, 1954, J. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Maslova, Rabinovich, et al., 1972, 2
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A.,
Specific heat and phase transitions of some alkyl compounds of silicon, germanium, and tin,
Tr. Khim. Khim. Tekhnol., 1972, (2), 44-50. [all data]
Notes
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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