Stannane, tetraethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-10.0 ± 0.62kcal/molReviewMartinho SimõesSelected data.
Δfgas-15.6 ± 1.5kcal/molReviewMartinho Simões 
Δfgas-10.5 ± 2.0kcal/molReviewMartinho Simões 
Δfgas-14.5 ± 2.0kcal/molReviewMartinho Simões 
Δfgas-40.51kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-22.1 ± 0.62kcal/molReviewMartinho SimõesSelected data.; MS
Δfliquid-27.7 ± 1.5kcal/molReviewMartinho SimõesMS
Δfliquid-22.6 ± 2.0kcal/molReviewMartinho SimõesMS
Δfliquid-26.6 ± 2.0kcal/molReviewMartinho SimõesMS
Δfliquid-52.61kcal/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcliquid-1551.0 ± 2.0kcal/molCC-SBTel'noi and Rabinovich, 1966Please also see Cox and Pilcher, 1970.; MS
Δcliquid-1551.5 ± 0.55kcal/molCC-SBDavies, Pope, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Δcliquid-1547.0 ± 2.0kcal/molCC-SBDillard, McNeill, et al., 1958MS
Δcliquid-1545.9 ± 1.5kcal/molCC-SBBalandin, Klabunovskii, et al., 1957Please also see Cox and Pilcher, 1970.; MS
Δcliquid-1521.0kcal/molCC-SBJones, Evans, et al., 1935MS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
72.11298.15Maslova, Rabinovich, et al., 1972T = 60 to 300 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Stannane, tetraethyl- (l) + Tin(IV) chloride (l) = C2H5Cl3Sn (l) + Stannane, chlorotriethyl- (l)

By formula: C8H20Sn (l) + Cl4Sn (l) = C2H5Cl3Sn (l) + C6H15ClSn (l)

Quantity Value Units Method Reference Comment
Δr-22.6 ± 1.1kcal/molRSC and ESTNash, Skinner, et al., 1965 

3Stannane, tetraethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotriethyl- (l)

By formula: 3C8H20Sn (l) + Cl4Sn (l) = 4C6H15ClSn (l)

Quantity Value Units Method Reference Comment
Δr-45.3 ± 2.2kcal/molRSC and ESTNash, Skinner, et al., 1965 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Tel'noi and Rabinovich, 1966
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1966, 40, 842. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Dillard, McNeill, et al., 1958
Dillard, C.R.; McNeill, E.H.; Simmons, D.E.; Yeldell, J.B., J. Am. Chem. Soc., 1958, 80, 3607. [all data]

Balandin, Klabunovskii, et al., 1957
Balandin, A.A.; Klabunovskii, E.I.; Kozina, M.P.; Ul'yanova, O.D., Izvest. Akad. Nauk SSSR Otdel. Khim. Nauk, 1957. [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Maslova, Rabinovich, et al., 1972
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transitions of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, (2), 44-50. [all data]

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]


Notes

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